Define particulate matter.
Distinguish between and .
A city records air pollution from a volcanic eruption, a construction site and the burning of vegetation to clear farmland.
Identify the natural source of primary air pollution.
Identify the two anthropogenic sources of primary air pollution.
Air pollutants were measured at three sites in the city of Bellford during the same weekday morning.

Identify the pollutant with the highest concentration at the industrial site.
Calculate the percentage decrease in concentration from the roadside site to the suburban park.
Explain the differences between the pollutant concentrations at the roadside and industrial sites.
An urban monitoring station detects carbon monoxide, sulfur dioxide and tropospheric ozone near a road and an industrial area.
Distinguish between a primary pollutant and a secondary pollutant.
Classify carbon monoxide and tropospheric ozone as primary or secondary pollutants.
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State two direct biological impacts of tropospheric ozone.
State two direct physical impacts of tropospheric ozone.
Four lakes lie at increasing distances downwind from a coal-fired industrial area. The bedrock beneath the lakes has a low capacity to neutralize acids.
Figure 2: Lake-water conditions at increasing distances downwind of an industrial area.
| Lake | Distance downwind / km | Lake-water pH | Dissolved aluminium / | Sensitive invertebrate taxa | Fish-egg survival / % |
|---|---|---|---|---|---|
| A | 10 | 4.3 | 290 | 3 | 12 |
| B | 30 | 4.7 | 220 | 5 | 28 |
| C | 60 | 5.5 | 105 | 9 | 63 |
| D | 100 | 6.4 | 35 | 14 | 88 |
State the lake with the greatest dissolved aluminium concentration.
Describe the relationship between lake-water pH and fish-egg survival.
Explain how acid deposition could produce the ecological patterns shown in Figure 2.
Lichen cover was recorded on comparable trees along a transect extending away from a busy urban road. A fixed-area quadrat was placed at the same height and compass-facing side of each trunk.

Describe the relationship shown in Figure 4.
Explain why lichens could be used as indicators of traffic-related air pollution in this study.
Suggest two reasons why Figure 4 does not prove that traffic pollution caused the observed pattern.
Sulfur dioxide and nitrogen oxides released in an urban area may contribute to acid deposition far from their sources.
State the acids formed from sulfur dioxide and nitrogen oxides in the atmosphere.
Explain why acid rain may occur far from the original emission source.
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A city beside an acidified lake proposes the following measures: replacing a coal-fired power station with renewable energy, installing a scrubber on the existing power station, and adding crushed limestone to the lake.
Identify which measure alters human activity, which controls pollution at the point of release, and which restores a damaged system.
Outline one limitation of adding crushed limestone to the lake.
A city council investigated air pollution along Central Avenue, a narrow street used by diesel buses and private vehicles. Monitoring was conducted at the roadside and in a park 300 m away.



Calculate the percentage by which the mean PM concentration was lower in the park than at the roadside station.
Describe two differences between air pollution at the roadside and in the park.
Explain why exposure to PM may present a greater respiratory risk than exposure to larger particles.
Evaluate which two proposed measures should be prioritized to reduce exposure to air pollution on Central Avenue.
Lichens were surveyed on trees along a transect extending away from the Marula Ring Road. The researchers also measured mean PM concentration at each distance.


Calculate the increase in mean lichen cover between 0 m and 200 m from the road.
Describe the relationship between distance from the road, PM concentration and lichen cover.
Explain how lichens may be used as an indicator of urban air pollution in this investigation.
Evaluate the conclusion that traffic pollution caused the observed change in lichen cover.
The central district of Riverton introduced a package of transport measures in 2025. It included a pedestrianized centre, protected cycle routes, more frequent electric buses and restricted access for high-emission cars.
Transport activity and annual mean air pollutant concentrations in Riverton central district before and after the 2025 transport measures.
| Indicator | 2024 | 2026 | Unit |
|---|---|---|---|
| Daily private-car entries | 82 000 | 49 000 | entries per day |
| Daily public-transport journeys | 46 000 | 68 000 | journeys per day |
| Daily cycling journeys | 12 000 | 25 000 | journeys per day |
| Annual mean concentration | 54 | 34 | |
| Annual mean concentration | 28 | 22 |
Calculate the percentage change in daily private-car entries between 2024 and 2026.
Compare the changes in and concentrations.
Suggest why the package of measures produced a larger reduction in than in .
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Concentrations of selected pollutants were monitored over a clear summer weekday in an urban area.

Identify the time of maximum tropospheric ozone concentration.
Determine the time lag between the maximum concentration and the maximum ozone concentration.
Explain the diurnal pattern of pollutants shown in Figure 5.
Air quality was compared on two summer days in a city located within a mountain basin. Traffic volume and industrial production were similar on both days.

Comparison of meteorological conditions and afternoon photochemical-smog pollutant concentrations on two summer days.
| Measurement | Day 1 | Day 2 |
|---|---|---|
| Mean wind speed / km h | 18 | 4 |
| Midday solar radiation / W m | 620 | 810 |
| Afternoon ozone / ppb | 48 | 108 |
| Afternoon PANs / ppb | 2 | 9 |
| Warm inversion layer | Absent | Present |
Compare the afternoon concentrations of ozone and PANs on the two days.
Analyse how the conditions shown could account for the greater photochemical-smog concentrations on Day 2.
Explain two ways in which acid deposition may cause a decline in a freshwater fish population.
Explain the formation of tropospheric ozone as a component of photochemical smog.
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Figure 1 compares normal atmospheric mixing with a temperature inversion above an urban basin.

Describe the temperature structure during the inversion shown in Figure 1.
Explain how the inversion and the urban basin can intensify photochemical smog.
A lower-income neighbourhood is located beside a major road and an industrial area. Many residents work outdoors and have limited access to healthcare.
Explain why the indirect impacts of tropospheric ozone may be greater in this neighbourhood than in a wealthier neighbourhood.
Emissions from the coal-burning Rovina power station have contributed to acid deposition in nearby Lake Oris. In 2021, crushed limestone was added to the lake.

Water quality and juvenile fish abundance in Lake Oris and an untreated control lake before and after liming.
| Lake | Year | Dissolved aluminium / | Juvenile fish / standardized survey | |
|---|---|---|---|---|
| Lake Oris | 2020 | 4.6 | 0.32 | 12 |
| Lake Oris | 2023 | 6.2 | 0.08 | 48 |
| Control lake | 2020 | 4.7 | 0.30 | 15 |
| Control lake | 2023 | 4.6 | 0.34 | 11 |

Distinguish between the sulfur dioxide emitted by the power station and the sulfuric acid deposited in Lake Oris.
Calculate the percentage decrease in dissolved aluminium concentration in Lake Oris from 2020 to 2023.
Explain how acid deposition may reduce fish populations in freshwater ecosystems.
Evaluate the management options for reducing the long-term impacts of emissions from the Rovina power station.
Between 2019 and 2025, the municipality of San Aurelio introduced a pedestrianized centre, compulsory catalytic converters for taxis, additional bus services and protected cycling routes.

Annual mean pollutant concentrations in San Aurelio urban centre.
| Pollutant | 2019 concentration | 2025 concentration | Unit |
|---|---|---|---|
| 54 | 31 | ||
| 29 | 21 | ||
| 48 | 39 | ||
| 1.4 | 0.7 |
Transport, active-travel and social indicators in San Aurelio, 2019 and 2025.
| Indicator | 2019 | 2025 |
|---|---|---|
| Private-car entries / day | 42 000 | 25 000 |
| Public-transport journeys / day | 68 000 | 92 000 |
| Cycling journeys / day | 7 000 | 19 000 |
| Pedestrian counts / day | 51 000 | 74 000 |
| Central retail footfall index | 100 | 113 |
| Low-income commuter cost index | 100 | 108 |
Calculate the percentage decrease in annual mean nitrogen dioxide concentration between 2019 and 2025.
Describe two changes in travel behaviour between 2019 and 2025.
Explain why the interventions may have produced different percentage reductions in the four pollutants.
Evaluate the overall success of San Aurelio's urban air-pollution strategy.
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Two neighbourhoods in the same city experienced a summer photochemical-smog episode. The neighbourhoods had similar population sizes, but differed in income, land use and access to services.
Figure 7: Neighbourhood indicators during the smog episode
| Indicator | East Junction | Hill Gardens |
|---|---|---|
| Mean afternoon ozone / ppb | 96 | 61 |
| Residents within 200 m of a major road / % | 72 | 18 |
| Outdoor workers / % of workforce | 31 | 9 |
| Asthma-related emergency visits / per 10 000 residents | 44 | 17 |
| Workdays lost / per 10 000 employed residents | 680 | 210 |
| Median household income / currency units | 24 000 | 71 000 |
| Residents within 15 min of a health clinic / % | 38 | 86 |
Calculate how many times greater the asthma-related emergency-visit rate was in East Junction than in Hill Gardens.
Distinguish between one direct impact and one indirect impact of tropospheric ozone supported by Figure 7.
Explain why the impacts of the smog episode were distributed unequally between the two neighbourhoods.
The city of San Aurelio is developing a strategy to reduce summer photochemical smog. An emissions inventory and modelled effects of four proposed measures are shown.

Modelled effects and annual public cost of four proposed air-pollution measures in San Aurelio.
| Proposed measure | reduction / % | VOC reduction / % | Peak ozone reduction / ppb | Annual public cost / million currency units |
|---|---|---|---|---|
| Compulsory low-emission vehicle zone | 24 | 7 | 11 | 46 |
| Solvent vapour standards | 1 | 28 | 8 | 14 |
| Industrial combustion controls | 12 | 5 | 5 | 31 |
| Free electric bus network | 18 | 6 | 9 | 72 |
Identify the largest source sector for each primary pollutant shown in Figure 8(a).
Explain why reducing both and VOC emissions may reduce peak summer ozone concentration.
Using Figures 8(a) and 8(b), suggest a justified two-measure strategy for San Aurelio.
Many rapidly growing cities experience traffic congestion while also seeking to increase access to employment and services.
Outline four links between anthropogenic activities and primary air pollutants in urban areas.
Explain how a combination of transport, regulatory and green-infrastructure interventions can reduce urban air pollution.
Using named real-world examples, evaluate the effectiveness of transport-centred strategies compared with technological and green-infrastructure strategies for managing urban air pollution.
Figure 2 shows diurnal changes in air pollutants measured at an urban monitoring station.

Calculate the time lag between the morning maximum in nitrogen monoxide and the maximum in tropospheric ozone.
Explain the difference in timing between these two maxima.
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At one urban monitoring station, the median daily maximum ozone concentration was before a low-emission zone was introduced and afterward. A Mann–Whitney test comparing the two periods gave . A significance level of was used.
Calculate the decrease in median daily maximum ozone concentration.
Interpret the result of the Mann–Whitney test.
Outline two reasons why these results do not prove that the low-emission zone caused the decrease.
Air pollutants and meteorological conditions were measured over one summer day in the city of Bellavista.

Meteorological measurements in Bellavista over one summer day.
| Time | Solar irradiance / W m | Wind speed / m s | Rainfall / mm |
|---|---|---|---|
| 06:00 | 0 | 0.5 | 0 |
| 08:00 | 210 | 0.8 | 0 |
| 10:00 | 560 | 1.0 | 0 |
| 12:00 | 830 | 1.2 | 0 |
| 13:00 | 890 | 1.0 | 0 |
| 15:00 | 780 | 1.3 | 0 |
| 16:00 | 620 | 1.5 | 0 |
| 17:00 | 430 | 2.5 | 0 |
| 19:00 | 120 | 4.5 | 0 |
| 22:00 | 0 | 3.5 | 0 |
Determine the time lag between the morning VOC maximum and the tropospheric ozone maximum.
Describe the diurnal variation in tropospheric ozone concentration.
Explain the delayed maximum in tropospheric ozone relative to the primary pollutants.
Explain how the meteorological conditions shown intensified photochemical smog during the afternoon.
Evaluate whether the data demonstrate that morning traffic was the sole cause of the afternoon ozone maximum.
The city of Valle Gris lies in a mountain basin. Air quality was monitored at the basin centre, an outer suburb and a ridge station during normal atmospheric conditions and during a winter temperature inversion.



Calculate the ratio of the concentration at the basin centre during inversion conditions to that during normal conditions.
Compare the spatial patterns of and tropospheric ozone during the temperature inversion.
Explain why the temperature inversion and basin topography produce high pollutant concentrations near the basin floor.
Evaluate strategies that Valle Gris could use to reduce exposure during future inversion events.
Researchers compared ozone exposure and selected social indicators in three districts of the city of Port Estela. A controlled crop experiment investigated the effects of ozone concentration on yield and leaf injury, and an annotated figure shows direct impacts of ozone on plants, people and materials.
Calculate the percentage by which respiratory clinic visits in Riverside exceeded those in Hillside.
Analyse the relationship between ozone exposure, income and the two health-related indicators across the three districts.
Explain how direct ozone damage may lead to indirect economic costs.
Evaluate how the city should respond to the unequal distribution of ozone impacts.
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Emissions of sulfur dioxide and nitrogen oxides from urban and industrial regions can affect ecosystems and settlements far downwind.
Explain the atmospheric formation of nitric acid and sulfuric acid from nitrogen oxides and sulfur dioxide.
Explain how acid deposition can affect terrestrial ecosystems, freshwater ecosystems, human health and buildings.
Using named real-world examples, evaluate strategies implemented before emissions occur, at the point of release, and after deposition or damage to reduce the environmental impacts of sulfur dioxide and nitrogen oxides.
A coastal city is expanding its port and housing areas. Major activities include diesel freight transport, demolition and construction, electricity generation and household biomass burning.
Distinguish between and and explain why particle size affects respiratory risk.
Analyse how the activities described could produce different urban air pollutants and how these pollutants could be reduced.
Using named real-world examples, discuss whether strict air-quality regulation can be achieved without increasing social inequality or limiting urban economic development.
In 2020, Northgate introduced a low-emission zone and regulations limiting VOC emissions from commercial solvents. Eastbank, a similar neighbouring urban area, did not introduce these policies. Monitoring continued at unchanged stations from 2016 to 2024. A statistical comparison of changes in annual mean ozone between the two areas gave .



Calculate the percentage decrease in annual mean tropospheric ozone concentration in Northgate between 2016 and 2024.
Using 2020 as the reference year, compare changes in the three pollutants from 2020 to 2024 in Northgate and Eastbank.
Explain why reducing both nitrogen oxides and VOC emissions may reduce photochemical smog.
Evaluate the conclusion that Northgate's policies caused the observed decrease in tropospheric ozone.
A warm, car-dependent city experiences recurring photochemical-smog episodes during clear summer weather. Vehicle exhaust, fuel vapours and solvent use are major emission sources.
Explain the formation of tropospheric ozone and peroxyacyl nitrates as components of photochemical smog.
Analyse why the highest concentrations of secondary pollutants may occur later in the day and downwind from the largest primary-emission sources.
Using named real-world examples, evaluate strategies for reducing photochemical smog in a warm, car-dependent city.
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A densely built inland city has high-rise street canyons, hot sunny summers, frequent temperature inversions and periods of weak wind. Smog episodes are most severe in central districts with limited open space.
Explain how a temperature inversion suppresses the vertical dispersion of urban air pollutants.
Analyse how the atmospheric conditions and urban form described could interact to intensify photochemical smog.
Using named real-world examples, evaluate whether changes to urban design are more effective than emergency responses for reducing the impacts of photochemical-smog episodes.
Tropospheric ozone may be distributed across a city unevenly, and the resulting health and economic burdens may differ between social groups.
Distinguish between direct biological, direct physical and indirect impacts of tropospheric ozone, giving one example of each.
Explain how direct exposure to tropospheric ozone can produce indirect costs that are distributed unequally across an urban population.
Using named real-world examples, to what extent can policies that reduce average urban ozone concentration also achieve environmental justice?