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B.4 Thermodynamics (Paper 2)

Practice exam-style IB Physics questions for Thermodynamics, aligned with the syllabus and grouped by topic. (Paper 2).

Paper 2
Difficulty
Status
Level
Question 1
HL • Paper 2
Easy
Calculator Permitted

A closed system receives 850 J by heating. At the same time, 320 J of work is done on the system.

1.

State the sign of WW for the system.

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2.

Calculate the change in internal energy of the system.

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Question 2
HL • Paper 2
Easy
Calculator Permitted
1.

Define entropy in terms of microscopic arrangements.

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2.

State the SI unit of entropy.

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Question 3
HL • Paper 2
Easy
Calculator Permitted

State the second law of thermodynamics in:

1.

State the second law of thermodynamics in Clausius form.

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2.

State the second law of thermodynamics in Kelvin form.

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3.

State the second law of thermodynamics in entropy form for an isolated system.

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Question 4
HL • Paper 2
Medium
Calculator Permitted

A gas expands at a constant pressure of 1.8×105 Pa1.8 \times 10^5\ \text{Pa} from 4.0×103 m34.0 \times 10^{-3}\ \text{m}^3 to 9.0×103 m39.0 \times 10^{-3}\ \text{m}^3.

1.

Calculate the work done by the gas.

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2.

State whether this work is positive or negative.

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Question 5
HL • Paper 2
Medium
Calculator Permitted

A sample of 0.75 mol of monatomic ideal gas is cooled from 420 K to 360 K.

1.

Calculate the change in internal energy of the gas.

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2.

State whether the answer depends on the path followed between the two temperatures.

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3.

Give a reason for your answer to (b).

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Question 6
HL • Paper 2
Medium
Calculator Permitted

A block melts reversibly at a constant temperature of 330 K330\ \text{K} while receiving 1.65×104 J1.65 \times 10^4\ \text{J} by heating.

1.

Calculate the entropy change of the block.

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2.

State the sign of the entropy change of the surroundings.

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Question 7
HL • Paper 2
Medium
Calculator Permitted

A simple model has 66 distinguishable counters. Each counter may be in the left or right half of a box.

1.

Determine the total number of microstates.

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2.

Determine the number of microstates for the macrostate with exactly 33 counters in the left half.

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3.

State why this macrostate is more likely than all 6 counters being in the left half.

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Question 8
HL • Paper 2
Medium
Calculator Permitted

Two different gases at the same temperature are separated by a removable partition in an insulated rigid container. The partition is removed and the gases mix.

Diagram of an insulated rigid container divided into two compartments by a removable partition, with gas A on one side and gas B on the other.
1.

State the change in total entropy of the gases.

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2.

Explain why the reverse process is not observed.

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Question 9
HL • Paper 2
Medium
Calculator Permitted

A plant grows ordered structures using energy from sunlight.

1.

State why the entropy of the plant itself may decrease.

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2.

Explain why this does not contradict the second law.

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Question 10
HL • Paper 2
Medium
Calculator Permitted

A gas undergoes an anticlockwise cycle on a P–V diagram.

P–V axes showing an anticlockwise closed loop with arrows and no numerical scale.
1.

State the sign of the net work done by the gas.

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2.

Explain what the enclosed area represents.

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3.

State the net change in internal energy for the cycle.

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Question 11
HL • Paper 2
Medium
Calculator Permitted

A gas process is shown on a P–V diagram.

P–V diagram with A to B as a vertical line at constant volume and B to C as a downward curving expansion path labelled as occurring at constant temperature, but without giving the process names.
1.

Identify the process ABA \to B.

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2.

State the work done during ABA \to B.

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3.

Identify the process BCB \to C.

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4.

State the relation between P and V for BCB \to C if the gas is ideal and the temperature is constant.

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Question 12
HL • Paper 2
Medium
Calculator Permitted

A monatomic ideal gas at pressure 2.4×105 Pa2.4 \times 10^5\ \mathrm{Pa} and volume 1.5×103 m31.5 \times 10^{-3}\ \mathrm{m}^3 undergoes an adiabatic expansion to volume 3.0×103 m33.0 \times 10^{-3}\ \mathrm{m}^3.

1.

State the adiabatic relation for this gas.

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2.

Calculate the final pressure.

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3.

State whether the temperature increases or decreases.

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Question 13
HL • Paper 2
Medium
Calculator Permitted

A heat engine takes 4.0 kJ4.0\ \text{kJ} from a hot reservoir and rejects 2.7 kJ2.7\ \text{kJ} to a cold reservoir in each cycle.

1.

Calculate the net work output per cycle.

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2.

Calculate the efficiency.

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3.

State the change in internal energy of the working gas over one complete cycle.

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Question 14
HL • Paper 2
Medium
Calculator Permitted

A power station heat engine has a hot reservoir at 820 K820\ \text{K} and a cold reservoir at 290 K290\ \text{K}.

1.

Calculate the Carnot efficiency.

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2.

State one practical reason why the actual efficiency is lower.

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Question 15
HL • Paper 2
Medium
Calculator Permitted

Compare an isothermal expansion and an adiabatic expansion of the same monatomic ideal gas, starting from the same state.

1.

State the value of ΔU\Delta U for the isothermal expansion.

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2.

State the value of QQ for the adiabatic expansion.

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3.

State which curve is steeper on a PPVV diagram.

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4.

Explain the reason for the difference in steepness.

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Question 16
HL • Paper 2
Medium
Calculator Permitted

A proposal claims that an engine operating between 500 K500\ \text{K} and 300 K300\ \text{K} can have an efficiency of 55%55\%.

1.

Calculate the Carnot efficiency for these reservoir temperatures.

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2.

Evaluate the claim.

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Question 17
HL • Paper 2
Hard
Calculator Permitted

A monatomic ideal gas in a cylinder is compressed rapidly by a piston. The cylinder is well insulated.

Diagram of an insulated cylinder with a movable piston compressing a fixed mass of gas; arrows show piston motion inward, with no numerical data.
1.

State the first law of thermodynamics using the Clausius sign convention, defining each term.

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2.

Explain why the temperature of the gas increases during the rapid insulated compression.

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Question 18
HL • Paper 2
Hard
Calculator Permitted

A fixed mass of monatomic ideal gas may undergo isovolumetric, isobaric, isothermal or adiabatic processes.

1.

Identify the PPVV graph shape for an isovolumetric and for an isobaric process.

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2.

Explain the energy transfers and internal-energy changes for isothermal and adiabatic expansions.

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Question 19
HL • Paper 2
Hard
Calculator Permitted

A student estimates work from a P–V graph for a gas expansion but uses only the rectangular area visible within the plotted grid. The graph axes do not start at zero.

P–V graph of an expansion curve drawn on axes with a false origin; pressure and volume axes begin at non-zero values, and the curve lies within a gridded rectangle.
1.

Describe how work done by a gas is obtained from a P–V graph.

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2.

Evaluate the student’s method and explain how a correct estimate should be made.

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Question 20
HL • Paper 2
Hard
Calculator Permitted

A gas expands isothermally into a larger volume while in thermal contact with a reservoir.

1.

Outline the microscopic meaning of entropy using S=kBlnΩS = k_B \ln \Omega.

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2.

Discuss how the entropy increase of the gas can be described both microscopically and macroscopically during the isothermal expansion.

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Question 21
HL • Paper 2
Hard
Calculator Permitted

The second law may be expressed in Clausius form, Kelvin form and entropy form.

1.

State the Clausius and Kelvin forms of the second law.

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2.

Compare these statements with the entropy form of the second law for reversible and irreversible processes in isolated systems.

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Question 22
HL • Paper 2
Hard
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A proposed engine cycle for a monatomic ideal gas consists of an isovolumetric heating stage, an adiabatic expansion stage and an isobaric compression stage returning to the initial state.

P–V diagram with three labelled stages forming a clockwise triangular-like cycle: vertical isovolumetric heating, curved adiabatic expansion, and horizontal isobaric compression back to the initial state.
1.

State how the net work and net change in internal energy are represented over a complete cycle on a P–V diagram.

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2.

Evaluate how the three stages could allow the device to operate as a heat engine, including the roles of heat input, heat rejection and irreversibility.

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Question 23
HL • Paper 2
Hard
Calculator Permitted

A heat engine is being designed to operate between a high-temperature reservoir and a lake used as the cold reservoir.

1.

Calculate the maximum efficiency if Th=900 KT_h = 900\ \text{K} and Tc=300 KT_c = 300\ \text{K}.

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2.

Discuss why this maximum efficiency cannot be exceeded and why a real high-power engine will be less efficient.

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Question 24
HL • Paper 2
Hard
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A claim is made that, because local entropy can decrease in living organisms and in freezing water, the second law cannot apply to the universe as a whole.

1.

Distinguish between isolated and non-isolated systems.

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2.

Evaluate the claim, referring to local entropy decrease, surroundings, irreversibility and the long-term evolution of the universe.

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B.3 Gas laws