A closed system receives 850 J by heating. At the same time, 320 J of work is done on the system.
State the sign of for the system.
Calculate the change in internal energy of the system.
Define entropy in terms of microscopic arrangements.
State the SI unit of entropy.
State the second law of thermodynamics in:
State the second law of thermodynamics in Clausius form.
State the second law of thermodynamics in Kelvin form.
State the second law of thermodynamics in entropy form for an isolated system.
A gas expands at a constant pressure of from to .
Calculate the work done by the gas.
State whether this work is positive or negative.
A sample of 0.75 mol of monatomic ideal gas is cooled from 420 K to 360 K.
Calculate the change in internal energy of the gas.
State whether the answer depends on the path followed between the two temperatures.
Give a reason for your answer to (b).
A block melts reversibly at a constant temperature of while receiving by heating.
Calculate the entropy change of the block.
State the sign of the entropy change of the surroundings.
A simple model has distinguishable counters. Each counter may be in the left or right half of a box.
Determine the total number of microstates.
Determine the number of microstates for the macrostate with exactly counters in the left half.
State why this macrostate is more likely than all 6 counters being in the left half.
Two different gases at the same temperature are separated by a removable partition in an insulated rigid container. The partition is removed and the gases mix.

State the change in total entropy of the gases.
Explain why the reverse process is not observed.
A plant grows ordered structures using energy from sunlight.
State why the entropy of the plant itself may decrease.
Explain why this does not contradict the second law.
A gas undergoes an anticlockwise cycle on a P–V diagram.

State the sign of the net work done by the gas.
Explain what the enclosed area represents.
State the net change in internal energy for the cycle.
A gas process is shown on a P–V diagram.

Identify the process .
State the work done during .
Identify the process .
State the relation between P and V for if the gas is ideal and the temperature is constant.
A monatomic ideal gas at pressure and volume undergoes an adiabatic expansion to volume .
State the adiabatic relation for this gas.
Calculate the final pressure.
State whether the temperature increases or decreases.
A heat engine takes from a hot reservoir and rejects to a cold reservoir in each cycle.
Calculate the net work output per cycle.
Calculate the efficiency.
State the change in internal energy of the working gas over one complete cycle.
A power station heat engine has a hot reservoir at and a cold reservoir at .
Calculate the Carnot efficiency.
State one practical reason why the actual efficiency is lower.
Compare an isothermal expansion and an adiabatic expansion of the same monatomic ideal gas, starting from the same state.
State the value of for the isothermal expansion.
State the value of for the adiabatic expansion.
State which curve is steeper on a – diagram.
Explain the reason for the difference in steepness.
A proposal claims that an engine operating between and can have an efficiency of .
Calculate the Carnot efficiency for these reservoir temperatures.
Evaluate the claim.
A monatomic ideal gas in a cylinder is compressed rapidly by a piston. The cylinder is well insulated.

State the first law of thermodynamics using the Clausius sign convention, defining each term.
Explain why the temperature of the gas increases during the rapid insulated compression.
A fixed mass of monatomic ideal gas may undergo isovolumetric, isobaric, isothermal or adiabatic processes.
Identify the – graph shape for an isovolumetric and for an isobaric process.
Explain the energy transfers and internal-energy changes for isothermal and adiabatic expansions.
A student estimates work from a P–V graph for a gas expansion but uses only the rectangular area visible within the plotted grid. The graph axes do not start at zero.

Describe how work done by a gas is obtained from a P–V graph.
Evaluate the student’s method and explain how a correct estimate should be made.
A gas expands isothermally into a larger volume while in thermal contact with a reservoir.
Outline the microscopic meaning of entropy using .
Discuss how the entropy increase of the gas can be described both microscopically and macroscopically during the isothermal expansion.
The second law may be expressed in Clausius form, Kelvin form and entropy form.
State the Clausius and Kelvin forms of the second law.
Compare these statements with the entropy form of the second law for reversible and irreversible processes in isolated systems.
A proposed engine cycle for a monatomic ideal gas consists of an isovolumetric heating stage, an adiabatic expansion stage and an isobaric compression stage returning to the initial state.

State how the net work and net change in internal energy are represented over a complete cycle on a P–V diagram.
Evaluate how the three stages could allow the device to operate as a heat engine, including the roles of heat input, heat rejection and irreversibility.
A heat engine is being designed to operate between a high-temperature reservoir and a lake used as the cold reservoir.
Calculate the maximum efficiency if and .
Discuss why this maximum efficiency cannot be exceeded and why a real high-power engine will be less efficient.
A claim is made that, because local entropy can decrease in living organisms and in freezing water, the second law cannot apply to the universe as a whole.
Distinguish between isolated and non-isolated systems.
Evaluate the claim, referring to local entropy decrease, surroundings, irreversibility and the long-term evolution of the universe.