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S3.1 The periodic table: Classification of elements

Practice exam-style IB Chemistry questions for The periodic table: Classification of elements, aligned with the syllabus and grouped by topic.

Verified by Dennis M.
Verified by Dennis M.
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Question 1
SL • Paper 1A
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SL • Paper 1A
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The p-block of the periodic table is represented by the shaded region in diagram

A.
B.
C.
D.
Question 2
SL • Paper 1A
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SL • Paper 1A
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The oxide in period 3 that is amphoteric is

A.

Al2O3Al_2O_3

B.

MgOMgO

C.

Na2ONa_2O

D.

SO3SO_3

Question 3
SL • Paper 1A
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SL • Paper 1A
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An atom has the electron configuration [Ne] 3s2 3p5[Ne]\ 3s^2\ 3p^5.

The period, group and classification of the element are

A.

period 5, group 17, noble gas

B.

period 3, group 15, halogen

C.

period 3, group 17, halogen

D.

period 3, group 18, noble gas

Question 4
SL • Paper 1A
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SL • Paper 1A
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Chlorine water is added to aqueous potassium iodide.

The equation for the reaction is

A.

Cl2(aq)+2K+(aq)→2KCl(aq)Cl_2(aq) + 2K^+(aq) \to 2KCl(aq)

B.

I2(aq)+2Cl−(aq)→2I−(aq)+Cl2(aq)I_2(aq) + 2Cl^-(aq) \to 2I^-(aq) + Cl_2(aq)

C.

Cl2(aq)+2I−(aq)→2Cl−(aq)+I2(aq)Cl_2(aq) + 2I^-(aq) \to 2Cl^-(aq) + I_2(aq)

D.

2Cl−(aq)+I2(aq)→Cl2(aq)+2I−(aq)2Cl^-(aq) + I_2(aq) \to Cl_2(aq) + 2I^-(aq)

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Question 5
SL • Paper 1A
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SL • Paper 1A
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The oxidation of hydrogen in CaH2CaH_2 is

A.

−1-1

B.

+1+1

C.

+2+2

D.

00

Question 6
HL • Paper 1A
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HL • Paper 1A
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The electron configuration of Cu2+Cu^{2+} is

A.

[Ar] 4s1 3d8[Ar]\ 4s^1\ 3d^8

B.

[Ar] 4s2 3d7[Ar]\ 4s^2\ 3d^7

C.

[Ar] 3d8[Ar]\ 3d^8

D.

[Ar] 3d9[Ar]\ 3d^9

Question 7
HL • Paper 1A
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HL • Paper 1A
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A transition metal complex absorbs orange light.

The colour most likely observed is

A.

green

B.

orange

C.

red

D.

blue

Question 8
SL • Paper 2
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SL • Paper 2
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A simplified periodic table is shown with three labelled positions, X, Y and Z.

A

the name given to a horizontal row in the periodic table.

[1]
B

the classification of element X and the number of valence electrons in an atom of X.

[2]
C

the classification of element Y as metal, non-metal or metalloid.

[1]

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Question 9
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SL • Paper 1A
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The species O2−O^{2-}, F−F^-, Na+Na^+ and Mg2+Mg^{2+} are isoelectronic.

The correct order of ionic radius, from largest to smallest, is

A.

F−>O2−>Na+>Mg2+F^- > O^{2-} > Na^+ > Mg^{2+}

B.

Mg2+>Na+>F−>O2−Mg^{2+} > Na^+ > F^- > O^{2-}

C.

O2−>Na+>F−>Mg2+O^{2-} > Na^+ > F^- > Mg^{2+}

D.

O2−>F−>Na+>Mg2+O^{2-} > F^- > Na^+ > Mg^{2+}

Question 10
HL • Paper 1A
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HL • Paper 1A
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The first ionization energy of aluminium is lower than that of magnesium.

The best explanation is that the electron removed from aluminium is

A.

paired in a 3p3p orbital, causing electron-electron repulsion

B.

closer to the nucleus because aluminium has a greater nuclear charge

C.

a 3s3s electron, which is more strongly shielded than a 3p3p electron

D.

a 3p3p electron, which is higher in energy than a 3s3s electron

Question 11
HL • Paper 1A
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HL • Paper 1A
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A transition element is an element that has an incomplete d sublevel in its atoms or forms at least one stable ion with an incomplete d sublevel.

The diagram that represents a transition element is

A.
B.
C.
D.
Question 12
HL • Paper 1A
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HL • Paper 1A
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A coloured complex absorbs light of wavelength 600 nm600\ \text{nm}.

Using c=λfc = \lambda f and c=3.00×108 m s−1c = 3.00 \times 10^8\ \text{m s}^{-1}, the frequency of the absorbed light is

A.

1.80×1011 s−11.80 \times 10^{11}\ \text{s}^{-1}

B.

5.00×1014 s−15.00 \times 10^{14}\ \text{s}^{-1}

C.

5.00×105 s−15.00 \times 10^5\ \text{s}^{-1}

D.

2.00×10−15 s−12.00 \times 10^{-15}\ \text{s}^{-1}

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Question 13
SL • Paper 2
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SL • Paper 2
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An atom of element E has the electron configuration [Ar]4s23d104p4[Ar]4s^23d^{10}4p^4.

A

the period and group number of element E.

[2]
B

the number of valence electrons and the block of the periodic table to which element E belongs.

[2]
Question 14
SL • Paper 2
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SL • Paper 2
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The graph shows periodic trends for selected period 3 elements.

Element

Atomic radius / pm

Electronegativity (Pauling)

Na

186

0.93

Mg

160

1.31

Al

143

1.61

Si

118

1.90

P

110

2.19

S

104

2.58

Cl

99

3.16

A

the trend in atomic radius across period 3 from sodium to chlorine.

[1]
B

the trend in atomic radius across period 3.

[2]
C

the general trend in electronegativity across period 3 from left to right.

[1]
Question 15
SL • Paper 2
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SL • Paper 2
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Group 1 metals react with water, and group 17 elements react with halide ions according to their reactivity trends.

A

Write the balanced equation for the reaction of potassium with water.

[2]
B

why chlorine displaces iodide ions from aqueous potassium iodide, but iodine does not displace chloride ions from aqueous potassium chloride.

[2]
Question 16
SL • Paper 2
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SL • Paper 2
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Oxides of elements show a change in acid-base character across a period.

A

Write the equation for the reaction of sodium oxide with water.

[1]
B

Write the equation for the reaction of sulfur trioxide with water.

[1]
C

how the acid-base character of the oxides changes across period 3 from sodium to sulfur.

[2]

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Question 17
SL • Paper 1B
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SL • Paper 1B
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The table gives information about four elements labelled A to D. The letters are not chemical symbols.

Element

Electron configuration

A

[Ne] 3s1[\text{Ne}]\,3s^1

B

[Ne] 3s2 3p4[\text{Ne}]\,3s^2\,3p^4

C

[Ar] 3d6 4s2[\text{Ar}]\,3d^6\,4s^2

D

[Ne] 3s2 3p2[\text{Ne}]\,3s^2\,3p^2

A

the period and group of element B from its electron configuration.

[2]
B

Identify the block and broad classification of element C.

[1]
C

why element D is classified as a metalloid rather than simply as a metal or non-metal.

[1]
Question 18
SL • Paper 1B
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SL • Paper 1B
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A simulation compares the reactions of three group 1 metals with excess water under the same conditions.

Group 1 metal

Time for reaction to finish / s

Temperature increase / ∘C^\circ\text{C}

Lithium

75

4

Sodium

30

8

Potassium

12

13

A

the gas produced in the reactions.

[1]
B

how the reactivity changes from lithium to potassium using the data.

[1]
C

the change in reactivity down group 1.

[2]
Question 19
HL • Paper 1A
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HL • Paper 1A
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Transition elements commonly show variable oxidation states.

The best explanation is that

A.

their filled p sublevels can expand into d sublevels

B.

their atoms have the same first ionization energy across the period

C.

their inner-shell electrons are removed before valence electrons

D.

their 4s4s and 3d3d electrons are relatively close in energy

Question 20
SL • Paper 2
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SL • Paper 2
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Oxidation states can be deduced using the usual rules and the overall charge of the species.

A

the oxidation of hydrogen in CaH2CaH_2 and oxygen in Na2O2Na_2O_2.

[2]
B

the oxidation of sulfur in SO42−SO_4^{2-} and give the systematic name of this oxyanion using a Roman numeral.

[2]

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Question 21
HL • Paper 2
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HL • Paper 2
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The graph shows first ionization energies for the elements in period 2.

A

the general trend in first ionization energy across period 2.

[1]
B

why the first ionization energy of boron is lower than that of beryllium.

[2]
C

why the first ionization energy of oxygen is lower than that of nitrogen.

[1]
Question 22
HL • Paper 2
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HL • Paper 2
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Zinc and scandium are both found in the first row of the d-block, but their classification as transition elements is considered differently.

A

Define the term transition element.

[1]
B

why zinc is not usually classified as a transition element.

[2]
C

one characteristic property commonly shown by transition elements that is linked to incomplete d-sublevels.

[1]
Question 23
HL • Paper 2
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HL • Paper 2
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Chromium and iron are first-row transition elements.

A

the condensed electron configuration of a chromium atom.

[1]
B

the electron configuration of Cr3+Cr^{3+}.

[1]
C

the electron configuration of Fe2+Fe^{2+}, given that FeFe is [Ar]4s23d6[Ar]4s^23d^6.

[1]
D

which sublevel loses electrons first when first-row transition metal atoms form ions.

[1]
Question 24
HL • Paper 2
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HL • Paper 2
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An aqueous transition metal complex absorbs light of wavelength 610 nm610\ \text{nm}. Use c=λfc=\lambda f and c=3.00×108 m s−1c=3.00\times 10^8\ \text{m s}^{-1}.

A

the frequency of the light absorbed.

[2]
B

the colour observed if the absorbed light is orange-red.

[1]
C

one factor that can affect the colour of a transition metal complex.

[1]

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Question 25
SL • Paper 1B
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SL • Paper 1B
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The graph shows first ionization energy, atomic radius and electronegativity for selected period 3 elements.

Element

First ionization energy / kJ mol−1^{-1}

Atomic radius / pm

Electronegativity / Pauling scale

Sodium (Na)

496

186

0.93

Magnesium (Mg)

738

160

1.31

Aluminium (Al)

578

143

1.61

Silicon (Si)

787

118

1.90

Phosphorus (P)

1012

110

2.19

Sulfur (S)

1000

104

2.58

Chlorine (Cl)

1251

99

3.16

A

the trend in atomic radius across the period shown.

[1]
B

the trend in atomic radius across the period.

[2]
C

Use the data to the element in the graph with the strongest attraction for bonding electrons, giving a reason.

[2]
Question 26
SL • Paper 1B
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SL • Paper 1B
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Aqueous halogens were added separately to aqueous solutions containing halide ions. The observations after mixing and shaking are shown.

Halogen added

Cl−(aq)Cl^-(aq)

Br−(aq)Br^-(aq)

I−(aq)I^-(aq)

Cl2Cl_2(aq)

no visible change

solution turns orange-brown

solution turns brown

Br2Br_2(aq)

no visible change

no visible change

solution turns brown

I2I_2(aq)

no visible change

no visible change

no visible change

A

Identify one mixture in which a displacement reaction occurs.

[1]
B

Write the ionic equation for the reaction between chlorine and bromide ions.

[2]
C

Use the observations to the order of decreasing reactivity of the three halogens.

[1]
Question 27
SL • Paper 1B
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SL • Paper 1B
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The table shows formulae of some compounds and ions containing hydrogen or oxygen. Some oxidation states are missing.

Species / formula

Given oxidation state(s)

Missing oxidation state

NaH\text{NaH}

Na = +1+1

H = ?

H2O2\text{H}_2\text{O}_2

H = +1+1

O = ?

NO3−\text{NO}_3^-

O = −2-2

N = ?

Cl2\text{Cl}_2

—

Cl = ?

A

the oxidation of hydrogen in sodium hydride, NaHNaH.

[1]
B

the oxidation of oxygen in hydrogen peroxide, H2O2H_2O_2.

[1]
C

the oxidation of nitrogen in NO3−NO_3^-.

[1]
D

why chlorine has oxidation zero in Cl2Cl_2.

[1]
Question 28
HL • Paper 1B
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HL • Paper 1B
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The table compares selected period 4 d-block elements and some of their common ions.

Element

Atom electron configuration

Common ion(s) / electron configuration

Sc

[Ar]4s23d1[Ar] 4s^2 3d^1

Sc2+=[Ar]3d1\text{Sc}^{2+} = [Ar] 3d^1; Sc3+=[Ar]\text{Sc}^{3+} = [Ar]

Ti

[Ar]4s23d2[Ar] 4s^2 3d^2

Ti2+=[Ar]3d2\text{Ti}^{2+} = [Ar] 3d^2

V

[Ar]4s23d3[Ar] 4s^2 3d^3

V2+=[Ar]3d3\text{V}^{2+} = [Ar] 3d^3

Fe

[Ar]4s23d6[Ar] 4s^2 3d^6

Fe2+=[Ar]3d6\text{Fe}^{2+} = [Ar] 3d^6

Cu

[Ar]4s13d10[Ar] 4s^1 3d^{10}

Cu2+=[Ar]3d9\text{Cu}^{2+} = [Ar] 3d^9

Zn

[Ar]4s23d10[Ar] 4s^2 3d^{10}

Zn2+=[Ar]3d10\text{Zn}^{2+} = [Ar] 3d^{10}

A

Using the data, identify the element that is d-block but is not normally classified as a transition element.

[1]
B

the identification in part (a) using electron configurations.

[2]
C

one argument for including scandium as a transition element, based on the data.

[1]

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Question 29
HL • Paper 2
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HL • Paper 2
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A table compares successive ionization energies for calcium and vanadium after the argon core.

Ionization energy

Ca / kJ mol−1^{-1}

V / kJ mol−1^{-1}

1st

590

650

2nd

1145

1414

3rd

4912

2830

4th

6491

4564

5th

8153

6290

A

what is meant by successive ionization energies.

[1]
B

why vanadium can form several oxidation states.

[2]
C

the electron configuration of V3+V^{3+}, given that VV is [Ar]4s23d3[Ar]4s^23d^3.

[1]
Question 30
HL • Paper 2
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HL • Paper 2
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A student uses colorimetry to the concentration of a coloured transition metal complex in solution.

A

how the calibration graph is used to the concentration of the unknown solution.

[2]
B

why a wavelength strongly absorbed by the complex is chosen for the colorimeter.

[2]
Question 31
SL • Paper 1B
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SL • Paper 1B
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Several period 3 oxides were added separately to water. Universal indicator and pH data were recorded after stirring.

Oxide

Indicator colour

pH

Na2ONa_2O

purple

13

MgOMgO

blue

10

Al2O3Al_2O_3

green

7

P4O10P_4O_{10}

red

2

SO2SO_2

red

2

A

Classify sodium oxide and sulfur dioxide as basic, acidic or amphoteric oxides.

[2]
B

Write an equation for the reaction of sodium oxide with water.

[1]
C

why the data support the idea that metallic and non-metallic properties form a continuum across period 3.

[2]
Question 32
HL • Paper 1B
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HL • Paper 1B
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The graph shows the first ionization energies of period 2 elements from lithium to neon.

A

the overall trend in first ionization energy across period 2.

[1]
B

the discontinuity between beryllium and boron.

[2]
C

the discontinuity between nitrogen and oxygen.

[2]

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Question 33
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HL • Paper 1B
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A transition metal complex appears blue-green in aqueous solution. A colour wheel and absorption spectrum for the solution are shown. Use c=λfc = \lambda f and c=3.00×108 m s−1c = 3.00 \times 10^8\ \text{m s}^{-1}.

A

the colour of light mainly absorbed by the complex.

[1]
B

the wavelength at maximum absorbance from the spectrum, in metres.

[1]
C

the frequency of light at maximum absorbance.

[2]
D

why absorption of this light gives rise to the observed colour.

[1]
Question 34
HL • Paper 1B
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HL • Paper 1B
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The table gives neutral atom electron configurations for chromium, iron and copper, and lists some ions formed by these elements.

Species

Electron configuration

Cr\text{Cr}

[Ar]4s1 3d5[\text{Ar}]4s^1\ 3d^5

Cr2+\text{Cr}^{2+}

[Ar]3d4[\text{Ar}]3d^4

Fe\text{Fe}

[Ar]4s2 3d6[\text{Ar}]4s^2\ 3d^6

Fe2+\text{Fe}^{2+}

[Ar]3d6[\text{Ar}]3d^6

Cu\text{Cu}

[Ar]4s1 3d10[\text{Ar}]4s^1\ 3d^{10}

Cu+\text{Cu}^{+}

[Ar]3d10[\text{Ar}]3d^{10}

Zn2+\text{Zn}^{2+}

[Ar]3d10[\text{Ar}]3d^{10}

A

the electron configuration of Fe3+Fe^{3+} from Fe:[Ar]4s23d6Fe: [Ar]4s^2 3d^6.

[1]
B

the electron configuration of Cu2+Cu^{2+} from Cu:[Ar]4s13d10Cu: [Ar]4s^1 3d^{10}.

[1]
C

the rule used to decide which electrons are removed first when first-row transition metal ions form.

[1]
D

Using the data, why copper(II) compounds are more likely to be coloured than zinc(II) compounds.

[1]
Question 35
SL • Paper 2
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SL • Paper 2
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The electron configurations of three neutral atoms are shown.

A: [Ne] 3s2 3p5[\text{Ne}]\ 3s^2\ 3p^5

B: [Ar] 4s2[\text{Ar}]\ 4s^2

C: [Ar] 4s2 3d10 4p3[\text{Ar}]\ 4s^2\ 3d^{10}\ 4p^3

A

Consider element A.

I.

the period, group and block of element A.

[3]
II.

why element A and bromine have similar chemical properties.

[2]
B

the classifications of elements B and C as metal, metalloid or non-metal, using their positions in the periodic table.

[2]
C

Hydrogen is often placed above group 1. why this placement does not make hydrogen an alkali metal.

[1]
Question 36
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SL • Paper 2
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The figure shows selected periodic trends for elements in period 3 and group 17.

Species

Series

Atomic radius / pm

Electronegativity / Pauling

Ionic radius / pm

Na

Period 3

186

0.9

—

Mg

Period 3

160

1.3

—

Al

Period 3

143

1.6

—

Si

Period 3

118

1.9

—

P

Period 3

110

2.2

—

S

Period 3

104

2.6

—

Cl

Period 3

99

3.2

—

F

Group 17

64

4.0

—

Cl

Group 17

99

3.2

—

Br

Group 17

114

3.0

—

I

Group 17

133

2.7

—

Mg2+^{2+}

Ion

—

—

72

A

Consider the elements from sodium to chlorine in period 3.

I.

the trends in atomic radius and electronegativity across this part of period 3.

[2]
II.

the trend in atomic radius across period 3.

[2]
B

Consider the halogens fluorine, chlorine, bromine and iodine.

I.

the trend in atomic radius down group 17.

[1]
II.

why electronegativity and non-metallic character decrease down group 17.

[2]
C

Magnesium commonly forms Mg2+Mg^{2+}. why the ionic radius of Mg2+Mg^{2+} is smaller than the atomic radius of Mg.

[1]

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Question 37
SL • Paper 2
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SL • Paper 2
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Oxidation states are assigned by treating bonds as if they were fully ionic. The species Na2O2Na_2O_2, CaH2CaH_2, NO3−NO_3^-, NO2−NO_2^- and Cl2Cl_2 are considered.

A

oxidation states in compounds and ions.

I.

the oxidation of oxygen in Na2O2Na_2O_2 and hydrogen in CaH2CaH_2.

[2]
II.

the oxidation of nitrogen in NO3−NO_3^- and NO2−NO_2^-, and give the systematic names using Roman numerals.

[3]
B

why the oxidation of chlorine in Cl2Cl_2 is zero.

[2]
Question 38
SL • Paper 2
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SL • Paper 2
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An element X was predicted before it was isolated. A modern description of X is that its neutral atom has the electron configuration [Ar] 4s2 3d10 4p2[\text{Ar}]\ 4s^2\ 3d^{10}\ 4p^2.

A

Use the electron configuration of X.

I.

the period, group and block of X.

[3]
II.

the likely identity of X and classify it as a metal, metalloid or non-metal.

[2]
B

how the organization of the periodic table can help chemists properties of undiscovered elements.

[2]
Question 39
HL • Paper 1B
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HL • Paper 1B
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Successive ionization energies are shown for two period 4 elements, X and Y. Element X forms several stable compounds with different oxidation states, whereas element Y mainly forms compounds in one oxidation .

A

what is meant by successive ionization energies.

[1]
B

Use the data to identify which element, X or Y, is more likely to be a transition element.

[1]
C

how the successive ionization energy data account for variable oxidation states in X.

[2]
D

the electron configuration of V3+V^{3+} from the neutral atom configuration V:[Ar]4s23d3V: [Ar]4s^2 3d^3.

[1]
Question 40
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HL • Paper 1B
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A student used colorimetry to the concentration of a coloured transition metal ion in an unknown solution. Standard solutions were prepared and their absorbance was measured at a selected wavelength.

A

Use the calibration graph to the concentration of the unknown solution.

[1]
B

why the wavelength selected should be close to the wavelength of maximum absorbance.

[2]
C

one source of systematic error in this colorimetric method.

[1]
D

The ligand around the metal ion is changed and the absorption maximum shifts to a shorter wavelength. what this indicates about the split d-sublevels.

[1]

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Question 41
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SL • Paper 2
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A class compares the reactions of group 1 metals with water and the displacement reactions of halogens with halide ions. Some observations are obtained from teacher demonstrations and some from simulations.

Reaction system

Observation

Lithium(s)+water(l)\text{Lithium}(s) + \text{water}(l)

gentle effervescence; moves slowly on the surface

Sodium(s)+water(l)\text{Sodium}(s) + \text{water}(l)

vigorous effervescence; metal melts into a ball and moves rapidly

Potassium(s)+water(l)\text{Potassium}(s) + \text{water}(l)

very vigorous effervescence; lilac flame observed

Bromine(aq)+chloride ions(aq)\text{Bromine}(aq) + \text{chloride ions}(aq)

no visible change; orange colour remains

Bromine(aq)+bromide ions(aq)\text{Bromine}(aq) + \text{bromide ions}(aq)

no visible change; orange colour remains

Bromine(aq)+iodide ions(aq)\text{Bromine}(aq) + \text{iodide ions}(aq)

orange solution turns brown

A

Potassium is added to water.

I.

Write a balanced equation for potassium reacting with water, including symbols.

[2]
II.

why the reactions of group 1 metals with water become more vigorous down the group.

[2]
B

whether aqueous bromine reacts with aqueous iodide ions and write the ionic equation if a reaction occurs.

[2]
C

the use of simulations rather than direct practical work for these reactivity comparisons.

[2]
Question 42
SL • Paper 2
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SL • Paper 2
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Oxides across a period show a change from basic metal oxides through amphoteric oxides to acidic non-metal oxides. The oxides Na2ONa_2O, MgOMgO, Al2O3Al_2O_3 and SO3SO_3 are considered.

A

Consider the reactions of oxides with water.

I.

equations for the reactions of Na2ONa_2O and SO3SO_3 with water.

[2]
II.

whether each solution formed in (a)(i) is acidic or alkaline, giving a reason.

[2]
B

, in terms of bonding, why metal oxides tend to be basic while non-metal oxides tend to be acidic.

[2]
C

how the behaviour of Al2O3Al_2O_3 supports the idea that metallic and non-metallic properties form a continuum.

[2]
Question 43
HL • Paper 2
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HL • Paper 2
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The graph shows first ionization energies for the period 2 elements from lithium to neon.

A

Consider the general pattern across period 2.

I.

the overall trend in first ionization energy from lithium to neon.

[1]
II.

the general increase in first ionization energy across period 2.

[2]
B

Consider the two discontinuities in the graph.

I.

why the first ionization energy of boron is lower than that of beryllium.

[2]
II.

why the first ionization energy of oxygen is lower than that of nitrogen. Do not base your answer on the phrase special stability of a half-filled sublevel.

[2]
C

how these discontinuities provide evidence for the existence of energy sublevels.

[1]
Question 44
HL • Paper 2
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HL • Paper 2
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Scandium, iron and zinc are d-block elements in period 4. Their common species include Sc3+Sc^{3+}, Fe2+Fe^{2+}, Fe3+Fe^{3+} and Zn2+Zn^{2+}.

A

Consider the classification of transition elements.

I.

the definition of a transition element used in this course.

[1]
II.

why zinc is not classified as a transition element.

[2]
III.

one argument for and one argument against including scandium as a transition element.

[2]
B

how incomplete d sublevels account for three characteristic properties of transition element compounds.

[3]

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Question 45
HL • Paper 2
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HL • Paper 2
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The first-row transition elements form ions by losing electrons from the 4s4s sublevel before the 3d3d sublevel. A graph comparing successive ionization energies for vanadium and calcium is shown.

A

electron configurations of vanadium and copper ions.

I.

the electron configuration of V3+V^{3+} from the neutral atom.

[2]
II.

the electron configurations of Cu+Cu^+ and Cu2+Cu^{2+}.

[2]
III.

why V5+V^{5+} has the electron configuration [Ar][\text{Ar}].

[1]
B

why variable oxidation states are common among transition elements.

[2]
C

Using the graph, why V5+V^{5+} is plausible but Ca5+Ca^{5+} is not.

[1]
Question 46
HL • Paper 2
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HL • Paper 2
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A transition metal complex appears blue-green in aqueous solution. It absorbs visible light of wavelength 6.10×10−7 m6.10 \times 10^{-7}\ \text{m}. Use c=3.00×108 m s−1c = 3.00 \times 10^8\ \text{m s}^{-1}.

A

Consider the origin of the colour.

I.

why many transition metal complexes are coloured.

[3]
II.

the frequency of the absorbed light.

[2]
B

The ligand is changed to one that causes a larger d-orbital splitting.

I.

If the dd-orbital splitting increases, the effect on the wavelength and frequency of the light absorbed.

[2]
II.

one factor, other than ligand identity, that can affect the colour of a transition metal complex.

[1]
Question 47
HL • Paper 2
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HL • Paper 2
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A student determines the concentration of a blue solution containing a transition metal complex using colorimetry. A calibration curve of absorbance against concentration is prepared from standard solutions.

A

Consider the design of the colorimetry method.

I.

why a wavelength near the absorption maximum should be selected.

[2]
II.

how the calibration curve is prepared.

[2]
B

The absorbance of a diluted sample corresponds on the calibration curve to 1.60×10−3 mol dm−31.60 \times 10^{-3}\ \text{mol dm}^{-3}. The original sample was diluted by transferring 10.0 cm310.0\ \text{cm}^3 into a 100.0 cm3100.0\ \text{cm}^3 volumetric flask and making up to the mark. the concentration of the original sample.

[2]
C

two ways to improve or check the reliability of the colorimetry result.

[2]
Question 48
HL • Paper 2
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HL • Paper 2
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The ions Fe2+Fe^{2+}, Fe3+Fe^{3+} and Zn2+Zn^{2+} are compared. Iron is also used as a heterogeneous catalyst in some industrial reactions.

A

Consider the electron configurations and magnetic behaviour of the ions.

I.

the electron configurations of Fe2+Fe^{2+} and Fe3+Fe^{3+}.

[2]
II.

why compounds containing iron ions may show magnetic properties whereas compounds containing Zn2+Zn^{2+} often do not.

[2]
B

why iron can show both catalytic behaviour and variable oxidation states.

[3]

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S2.4 From models to materials

S3.2 Functional groups