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S3.1 The periodic table: Classification of elements

Practice exam-style IB Chemistry questions for The periodic table: Classification of elements, aligned with the syllabus and grouped by topic.

Verified by Dennis M.
Verified by Dennis M.
Paper
Difficulty
Status
Level
Question 1
SL • Paper 1A
Easy
Calculator Permitted

The p-block of the periodic table is represented by the shaded region in diagram

A.
B.
C.
D.
Question 2
SL • Paper 1A
Easy
Calculator Permitted

The oxide in period 3 that is amphoteric is

A.

Al2O3Al_2O_3

B.

MgOMgO

C.

Na2ONa_2O

D.

SO3SO_3

Question 3
SL • Paper 1A
Easy
Calculator Permitted

An atom has the electron configuration [Ne] 3s2 3p5[Ne]\ 3s^2\ 3p^5.

The period, group and classification of the element are

A.

period 5, group 17, noble gas

B.

period 3, group 15, halogen

C.

period 3, group 17, halogen

D.

period 3, group 18, noble gas

Question 4
SL • Paper 1A
Easy
Calculator Permitted

Chlorine water is added to aqueous potassium iodide.

The equation for the reaction is

A.

Cl2(aq)+2K+(aq)2KCl(aq)Cl_2(aq) + 2K^+(aq) \to 2KCl(aq)

B.

I2(aq)+2Cl(aq)2I(aq)+Cl2(aq)I_2(aq) + 2Cl^-(aq) \to 2I^-(aq) + Cl_2(aq)

C.

Cl2(aq)+2I(aq)2Cl(aq)+I2(aq)Cl_2(aq) + 2I^-(aq) \to 2Cl^-(aq) + I_2(aq)

D.

2Cl(aq)+I2(aq)Cl2(aq)+2I(aq)2Cl^-(aq) + I_2(aq) \to Cl_2(aq) + 2I^-(aq)

Question 5
SL • Paper 1A
Easy
Calculator Permitted

The oxidation state of hydrogen in CaH2CaH_2 is

A.

1-1

B.

+1+1

C.

+2+2

D.

00

Question 6
HL • Paper 1A
Easy
Calculator Permitted

The electron configuration of Cu2+Cu^{2+} is

A.

[Ar] 4s1 3d8[Ar]\ 4s^1\ 3d^8

B.

[Ar] 4s2 3d7[Ar]\ 4s^2\ 3d^7

C.

[Ar] 3d8[Ar]\ 3d^8

D.

[Ar] 3d9[Ar]\ 3d^9

Question 7
HL • Paper 1A
Easy
Calculator Permitted

A transition metal complex absorbs orange light.

The colour most likely observed is

A simple colour wheel showing the visible colours arranged around a circle with opposite colours clearly placed across from one another. The wheel should indicate that orange and blue are complementary colours.
A.

green

B.

orange

C.

red

D.

blue

Question 8
SL • Paper 2
Easy
Calculator Permitted

A simplified periodic table is shown with three labelled positions, X, Y and Z.

A simplified outline of the periodic table showing the s-block on the left, d-block in the centre and p-block on the right. Position X is in period 3, group 17. Position Y is on the stepped boundary between metals and non-metals. Position Z is in the central d-block. Group and period labels are visible, but element names are not shown.
A

State the name given to a horizontal row in the periodic table.

[1]
Write your answer here...
B

State the classification of element X and the number of valence electrons in an atom of X.

[2]
Write your answer here...
C

State the classification of element Y as metal, non-metal or metalloid.

[1]
Write your answer here...

0

Question 9
SL • Paper 1A
Medium
Calculator Permitted

The species O2O^{2-}, FF^-, Na+Na^+ and Mg2+Mg^{2+} are isoelectronic.

The correct order of ionic radius, from largest to smallest, is

A.

F>O2>Na+>Mg2+F^- > O^{2-} > Na^+ > Mg^{2+}

B.

Mg2+>Na+>F>O2Mg^{2+} > Na^+ > F^- > O^{2-}

C.

O2>Na+>F>Mg2+O^{2-} > Na^+ > F^- > Mg^{2+}

D.

O2>F>Na+>Mg2+O^{2-} > F^- > Na^+ > Mg^{2+}

Question 10
HL • Paper 1A
Medium
Calculator Permitted

The first ionization energy of aluminium is lower than that of magnesium.

The best explanation is that the electron removed from aluminium is

A.

paired in a 3p3p orbital, causing electron-electron repulsion

B.

closer to the nucleus because aluminium has a greater nuclear charge

C.

a 3s3s electron, which is more strongly shielded than a 3p3p electron

D.

a 3p3p electron, which is higher in energy than a 3s3s electron

Question 11
HL • Paper 1A
Medium
Calculator Permitted

A transition element is an element that has an incomplete d sublevel in its atoms or forms at least one stable ion with an incomplete d sublevel.

The diagram that represents a transition element is

A.
B.
C.
D.
Question 12
HL • Paper 1A
Medium
Calculator Permitted

A coloured complex absorbs light of wavelength 600 nm600\ \text{nm}.

Using c=λfc = \lambda f and c=3.00×108 m s1c = 3.00 \times 10^8\ \text{m s}^{-1}, the frequency of the absorbed light is

A.

1.80×1011 s11.80 \times 10^{11}\ \text{s}^{-1}

B.

5.00×1014 s15.00 \times 10^{14}\ \text{s}^{-1}

C.

5.00×105 s15.00 \times 10^5\ \text{s}^{-1}

D.

2.00×1015 s12.00 \times 10^{-15}\ \text{s}^{-1}

Question 13
SL • Paper 2
Medium
Calculator Permitted

An atom of element E has the electron configuration [Ar]4s23d104p4[Ar]4s^23d^{10}4p^4.

A

Deduce the period and group number of element E.

[2]
Write your answer here...
B

Deduce the number of valence electrons and the block of the periodic table to which element E belongs.

[2]
Write your answer here...

0

Question 14
SL • Paper 2
Medium
Calculator Permitted

The graph shows periodic trends for selected period 3 elements.

ElementAtomic radius / pmElectronegativity (Pauling)
Na1860.93
Mg1601.31
Al1431.61
Si1181.90
P1102.19
S1042.58
Cl993.16
A

Describe the trend in atomic radius across period 3 from sodium to chlorine.

[1]
Write your answer here...
B

Explain the trend in atomic radius across period 3.

[2]
Write your answer here...
C

State the general trend in electronegativity across period 3 from left to right.

[1]
Write your answer here...

0

Question 15
SL • Paper 2
Medium
Calculator Permitted

Group 1 metals react with water, and group 17 elements react with halide ions according to their reactivity trends.

A

Write the balanced equation for the reaction of potassium with water.

[2]
Write your answer here...
B

Explain why chlorine displaces iodide ions from aqueous potassium iodide, but iodine does not displace chloride ions from aqueous potassium chloride.

[2]
Write your answer here...

0

Question 16
SL • Paper 2
Medium
Calculator Permitted

Oxides of elements show a change in acid-base character across a period.

A

Write the equation for the reaction of sodium oxide with water.

[1]
Write your answer here...
B

Write the equation for the reaction of sulfur trioxide with water.

[1]
Write your answer here...
C

Outline how the acid-base character of the oxides changes across period 3 from sodium to sulfur.

[2]
Write your answer here...

0

Question 17
SL • Paper 1B
Medium
Calculator Permitted

The table gives information about four elements labelled A to D. The letters are not chemical symbols.

ElementElectron configuration
A[Ne] 3s1
B[Ne] 3s2 3p4
C[Ar] 3d6 4s2
D[Ne] 3s2 3p2
A

Deduce the period and group of element B from its electron configuration.

[2]
Write your answer here...
B

Identify the block and broad classification of element C.

[1]
Write your answer here...
C

Suggest why element D is classified as a metalloid rather than simply as a metal or non-metal.

[1]
Write your answer here...

0

Question 18
SL • Paper 1B
Medium
Calculator Permitted

A simulation compares the reactions of three group 1 metals with excess water under the same conditions.

Group 1 metalTime for reaction to finish / sTemperature increase / °C
Lithium754
Sodium308
Potassium1213
A

State the gas produced in the reactions.

[1]
Write your answer here...
B

Describe how the reactivity changes from lithium to potassium using the data.

[1]
Write your answer here...
C

Explain the change in reactivity down group 1.

[2]
Write your answer here...

0

Question 19
HL • Paper 1A
Medium
Calculator Permitted

Transition elements commonly show variable oxidation states.

The best explanation is that

A.

their filled p sublevels can expand into d sublevels

B.

their atoms have the same first ionization energy across the period

C.

their inner-shell electrons are removed before valence electrons

D.

their 4s4s and 3d3d electrons are relatively close in energy

Question 20
SL • Paper 2
Medium
Calculator Permitted

Oxidation states can be deduced using the usual rules and the overall charge of the species.

A

Deduce the oxidation state of hydrogen in CaH2CaH_2 and oxygen in Na2O2Na_2O_2.

[2]
Write your answer here...
B

Deduce the oxidation state of sulfur in SO42SO_4^{2-} and give the systematic name of this oxyanion using a Roman numeral.

[2]
Write your answer here...

0

Question 21
HL • Paper 2
Medium
Calculator Permitted

The graph shows first ionization energies for the elements in period 2.

First ionization energy vs atomic number for period 2.
A

State the general trend in first ionization energy across period 2.

[1]
Write your answer here...
B

Explain why the first ionization energy of boron is lower than that of beryllium.

[2]
Write your answer here...
C

Explain why the first ionization energy of oxygen is lower than that of nitrogen.

[1]
Write your answer here...

0

Question 22
HL • Paper 2
Medium
Calculator Permitted

Zinc and scandium are both found in the first row of the d-block, but their classification as transition elements is considered differently.

A

Define the term transition element.

[1]
Write your answer here...
B

Explain why zinc is not usually classified as a transition element.

[2]
Write your answer here...
C

State one characteristic property commonly shown by transition elements that is linked to incomplete d-sublevels.

[1]
Write your answer here...

0

Question 23
HL • Paper 2
Medium
Calculator Permitted

Chromium and iron are first-row transition elements.

A

State the condensed electron configuration of a chromium atom.

[1]
Write your answer here...
B

Deduce the electron configuration of Cr3+Cr^{3+}.

[1]
Write your answer here...
C

Deduce the electron configuration of Fe2+Fe^{2+}, given that FeFe is [Ar]4s23d6[Ar]4s^23d^6.

[1]
Write your answer here...
D

State which sublevel loses electrons first when first-row transition metal atoms form ions.

[1]
Write your answer here...

0

Question 24
HL • Paper 2
Medium
Calculator Permitted

An aqueous transition metal complex absorbs light of wavelength 610 nm610\ \text{nm}. Use c=λfc=\lambda f and c=3.00×108 m s1c=3.00\times 10^8\ \text{m s}^{-1}.

A

Calculate the frequency of the light absorbed.

[2]
Write your answer here...
B

Deduce the colour observed if the absorbed light is orange-red.

[1]
Write your answer here...
C

State one factor that can affect the colour of a transition metal complex.

[1]
Write your answer here...

0

Question 25
SL • Paper 1B
Medium
Calculator Permitted

The graph shows first ionization energy, atomic radius and electronegativity for selected period 3 elements.

ElementFirst ionization energy / kJ mol^-1Atomic radius / pmElectronegativity / Pauling scale
Sodium (Na)4961860.93
Magnesium (Mg)7381601.31
Aluminium (Al)5781431.61
Silicon (Si)7871181.90
Phosphorus (P)10121102.19
Sulfur (S)10001042.58
Chlorine (Cl)1251993.16
A

Describe the trend in atomic radius across the period shown.

[1]
Write your answer here...
B

Explain the trend in atomic radius across the period.

[2]
Write your answer here...
C

Use the data to suggest the element in the graph with the strongest attraction for bonding electrons, giving a reason.

[2]
Write your answer here...

0

Question 26
SL • Paper 1B
Medium
Calculator Permitted

Aqueous halogens were added separately to aqueous solutions containing halide ions. The observations after mixing and shaking are shown.

Halogen addedCl⁻(aq)Br⁻(aq)I⁻(aq)
Cl₂(aq)no visible changesolution turns orange-brownsolution turns brown
Br₂(aq)no visible changeno visible changesolution turns brown
I₂(aq)no visible changeno visible changeno visible change
A

Identify one mixture in which a displacement reaction occurs.

[1]
Write your answer here...
B

Write the ionic equation for the reaction between chlorine and bromide ions.

[2]
Write your answer here...
C

Use the observations to deduce the order of decreasing reactivity of the three halogens.

[1]
Write your answer here...

0

Question 27
SL • Paper 1B
Medium
Calculator Permitted

The table shows formulae of some compounds and ions containing hydrogen or oxygen. Some oxidation states are missing.

Species / formulaGiven oxidation state(s)Missing oxidation state
NaHNa = +1H = ?
H2O2H = +1O = ?
NO3−O = -2N = ?
Cl2Cl = ?
A

Deduce the oxidation state of hydrogen in sodium hydride, NaHNaH.

[1]
Write your answer here...
B

Deduce the oxidation state of oxygen in hydrogen peroxide, H2O2H_2O_2.

[1]
Write your answer here...
C

Deduce the oxidation state of nitrogen in NO3NO_3^-.

[1]
Write your answer here...
D

Explain why chlorine has oxidation state zero in Cl2Cl_2.

[1]
Write your answer here...

0

Question 28
HL • Paper 1B
Medium
Calculator Permitted

The table compares selected period 4 d-block elements and some of their common ions.

ElementAtom electron configurationCommon ion(s) / electron configuration
Sc[Ar] 4s2 3d1Sc2+ = [Ar] 3d1; Sc3+ = [Ar]
Ti[Ar] 4s2 3d2Ti2+ = [Ar] 3d2
V[Ar] 4s2 3d3V2+ = [Ar] 3d3
Fe[Ar] 4s2 3d6Fe2+ = [Ar] 3d6
Cu[Ar] 4s1 3d10Cu2+ = [Ar] 3d9
Zn[Ar] 4s2 3d10Zn2+ = [Ar] 3d10
A

Using the data, identify the element that is d-block but is not normally classified as a transition element.

[1]
Write your answer here...
B

Explain the identification in part (a) using electron configurations.

[2]
Write your answer here...
C

Evaluate one argument for including scandium as a transition element, based on the data.

[1]
Write your answer here...

0

Question 29
HL • Paper 2
Medium
Calculator Permitted

A table compares successive ionization energies for calcium and vanadium after the argon core.

Ionization energyCa / kJ mol^-1V / kJ mol^-1
1st590650
2nd11451414
3rd49122830
4th64914564
5th81536290
A

State what is meant by successive ionization energies.

[1]
Write your answer here...
B

Explain why vanadium can form several oxidation states.

[2]
Write your answer here...
C

Deduce the electron configuration of V3+V^{3+}, given that VV is [Ar]4s23d3[Ar]4s^23d^3.

[1]
Write your answer here...

0

Question 30
HL • Paper 2
Medium
Calculator Permitted

A student uses colorimetry to determine the concentration of a coloured transition metal complex in solution.

Calibration graph for a coloured transition metal complex at one fixed wavelength.
A

Outline how the calibration graph is used to determine the concentration of the unknown solution.

[2]
Write your answer here...
B

Explain why a wavelength strongly absorbed by the complex is chosen for the colorimeter.

[2]
Write your answer here...

0

Question 31
SL • Paper 1B
Hard
Calculator Permitted

Several period 3 oxides were added separately to water. Universal indicator and pH data were recorded after stirring.

OxideIndicator colourpH
Na2Opurple13
MgOblue10
Al2O3green7
P4O10red2
SO2red2
A

Classify sodium oxide and sulfur dioxide as basic, acidic or amphoteric oxides.

[2]
Write your answer here...
B

Write an equation for the reaction of sodium oxide with water.

[1]
Write your answer here...
C

Explain why the data support the idea that metallic and non-metallic properties form a continuum across period 3.

[2]
Write your answer here...

0

Question 32
HL • Paper 1B
Hard
Calculator Permitted

The graph shows the first ionization energies of period 2 elements from lithium to neon.

First ionization energies of the period 2 elements from lithium to neon.
A

Describe the overall trend in first ionization energy across period 2.

[1]
Write your answer here...
B

Explain the discontinuity between beryllium and boron.

[2]
Write your answer here...
C

Explain the discontinuity between nitrogen and oxygen.

[2]
Write your answer here...

0

Question 33
HL • Paper 1B
Hard
Calculator Permitted

A transition metal complex appears blue-green in aqueous solution. A colour wheel and absorption spectrum for the solution are shown. Use c=λfc = \lambda f and c=3.00×108 m s1c = 3.00 \times 10^8\ \text{m s}^{-1}.

Absorption spectrum of a transition-metal complex solution.
A

State the colour of light mainly absorbed by the complex.

[1]
Write your answer here...
B

Determine the wavelength at maximum absorbance from the spectrum, in metres.

[1]
Write your answer here...
C

Calculate the frequency of light at maximum absorbance.

[2]
Write your answer here...
D

Explain why absorption of this light gives rise to the observed colour.

[1]
Write your answer here...

0

Question 34
HL • Paper 1B
Hard
Calculator Permitted

The table gives neutral atom electron configurations for chromium, iron and copper, and lists some ions formed by these elements.

SpeciesElectron configuration
Cr[Ar]4s1 3d5
Cr2+[Ar]3d4
Fe[Ar]4s2 3d6
Fe2+[Ar]3d6
Cu[Ar]4s1 3d10
Cu+[Ar]3d10
Zn2+[Ar]3d10
A

Deduce the electron configuration of Fe3+Fe^{3+} from Fe:[Ar]4s23d6Fe: [Ar]4s^2 3d^6.

[1]
Write your answer here...
B

Deduce the electron configuration of Cu2+Cu^{2+} from Cu:[Ar]4s13d10Cu: [Ar]4s^1 3d^{10}.

[1]
Write your answer here...
C

Outline the rule used to decide which electrons are removed first when first-row transition metal ions form.

[1]
Write your answer here...
D

Using the data, suggest why copper(II) compounds are more likely to be coloured than zinc(II) compounds.

[1]
Write your answer here...

0

Question 35
SL • Paper 2
Hard
Calculator Permitted

The electron configurations of three neutral atoms are shown.

A: [Ne] 3s2 3p5[\text{Ne}]\ 3s^2\ 3p^5

B: [Ar] 4s2[\text{Ar}]\ 4s^2

C: [Ar] 4s2 3d10 4p3[\text{Ar}]\ 4s^2\ 3d^{10}\ 4p^3

A

Consider element A.

I.

Deduce the period, group and block of element A.

[3]
Write your answer here...
II.

Explain why element A and bromine have similar chemical properties.

[2]
Write your answer here...
B

Compare the classifications of elements B and C as metal, metalloid or non-metal, using their positions in the periodic table.

[2]
Write your answer here...
C

Hydrogen is often placed above group 1. Suggest why this placement does not make hydrogen an alkali metal.

[1]
Write your answer here...

0

Question 36
SL • Paper 2
Hard
Calculator Permitted

The figure shows selected periodic trends for elements in period 3 and group 17.

SpeciesSeriesAtomic radius / pmElectronegativity / PaulingIonic radius / pm
NaPeriod 31860.9
MgPeriod 31601.3
AlPeriod 31431.6
SiPeriod 31181.9
PPeriod 31102.2
SPeriod 31042.6
ClPeriod 3993.2
FGroup 17644.0
ClGroup 17993.2
BrGroup 171143.0
IGroup 171332.7
Mg2+Ion72
A

Consider the elements from sodium to chlorine in period 3.

I.

Describe the trends in atomic radius and electronegativity across this part of period 3.

[2]
Write your answer here...
II.

Explain the trend in atomic radius across period 3.

[2]
Write your answer here...
B

Consider the halogens fluorine, chlorine, bromine and iodine.

I.

State the trend in atomic radius down group 17.

[1]
Write your answer here...
II.

Explain why electronegativity and non-metallic character decrease down group 17.

[2]
Write your answer here...
C

Magnesium commonly forms Mg2+Mg^{2+}. Suggest why the ionic radius of Mg2+Mg^{2+} is smaller than the atomic radius of Mg.

[1]
Write your answer here...

0

Question 37
SL • Paper 2
Hard
Calculator Permitted

Oxidation states are assigned by treating bonds as if they were fully ionic. The species Na2O2Na_2O_2, CaH2CaH_2, NO3NO_3^-, NO2NO_2^- and Cl2Cl_2 are considered.

A

Deduce oxidation states in compounds and ions.

I.

Deduce the oxidation state of oxygen in Na2O2Na_2O_2 and hydrogen in CaH2CaH_2.

[2]
Write your answer here...
II.

Deduce the oxidation state of nitrogen in NO3NO_3^- and NO2NO_2^-, and give the systematic names using Roman numerals.

[3]
Write your answer here...
B

Explain why the oxidation state of chlorine in Cl2Cl_2 is zero.

[2]
Write your answer here...

0

Question 38
SL • Paper 2
Hard
Calculator Permitted

An element X was predicted before it was isolated. A modern description of X is that its neutral atom has the electron configuration [Ar] 4s2 3d10 4p2[\text{Ar}]\ 4s^2\ 3d^{10}\ 4p^2.

A

Use the electron configuration of X.

I.

Deduce the period, group and block of X.

[3]
Write your answer here...
II.

Deduce the likely identity of X and classify it as a metal, metalloid or non-metal.

[2]
Write your answer here...
B

Discuss how the organization of the periodic table can help chemists predict properties of undiscovered elements.

[2]
Write your answer here...

0

Question 39
HL • Paper 1B
Hard
Calculator Permitted

Successive ionization energies are shown for two period 4 elements, X and Y. Element X forms several stable compounds with different oxidation states, whereas element Y mainly forms compounds in one oxidation state.

Successive ionization energies for two period 4 elements.
A

State what is meant by successive ionization energies.

[1]
Write your answer here...
B

Use the data to identify which element, X or Y, is more likely to be a transition element.

[1]
Write your answer here...
C

Explain how the successive ionization energy data account for variable oxidation states in X.

[2]
Write your answer here...
D

Deduce the electron configuration of V3+V^{3+} from the neutral atom configuration V:[Ar]4s23d3V: [Ar]4s^2 3d^3.

[1]
Write your answer here...

0

Question 40
HL • Paper 1B
Hard
Calculator Permitted

A student used colorimetry to determine the concentration of a coloured transition metal ion in an unknown solution. Standard solutions were prepared and their absorbance was measured at a selected wavelength.

Calibration graph with standards and an unknown absorbance line.
A

Use the calibration graph to determine the concentration of the unknown solution.

[1]
Write your answer here...
B

Explain why the wavelength selected should be close to the wavelength of maximum absorbance.

[2]
Write your answer here...
C

Suggest one source of systematic error in this colorimetric method.

[1]
Write your answer here...
D

The ligand around the metal ion is changed and the absorption maximum shifts to a shorter wavelength. Explain what this indicates about the split d-sublevels.

[1]
Write your answer here...

0

Question 41
SL • Paper 2
Hard
Calculator Permitted

A class compares the reactions of group 1 metals with water and the displacement reactions of halogens with halide ions. Some observations are obtained from teacher demonstrations and some from simulations.

Reaction systemObservation
Lithium(s) + water(l)gentle effervescence; moves slowly on the surface
Sodium(s) + water(l)vigorous effervescence; metal melts into a ball and moves rapidly
Potassium(s) + water(l)very vigorous effervescence; lilac flame observed
Bromine(aq) + chloride ions(aq)no visible change; orange colour remains
Bromine(aq) + bromide ions(aq)no visible change; orange colour remains
Bromine(aq) + iodide ions(aq)orange solution turns brown
A

Potassium is added to water.

I.

Write a balanced equation for potassium reacting with water, including state symbols.

[2]
Write your answer here...
II.

Explain why the reactions of group 1 metals with water become more vigorous down the group.

[2]
Write your answer here...
B

Deduce whether aqueous bromine reacts with aqueous iodide ions and write the ionic equation if a reaction occurs.

[2]
Write your answer here...
C

Evaluate the use of simulations rather than direct practical work for these reactivity comparisons.

[2]
Write your answer here...

0

Question 42
SL • Paper 2
Hard
Calculator Permitted

Oxides across a period show a change from basic metal oxides through amphoteric oxides to acidic non-metal oxides. The oxides Na2ONa_2O, MgOMgO, Al2O3Al_2O_3 and SO3SO_3 are considered.

A

Consider the reactions of oxides with water.

I.

Deduce equations for the reactions of Na2ONa_2O and SO3SO_3 with water.

[2]
Write your answer here...
II.

Predict whether each solution formed in (a)(i) is acidic or alkaline, giving a reason.

[2]
Write your answer here...
B

Explain, in terms of bonding, why metal oxides tend to be basic while non-metal oxides tend to be acidic.

[2]
Write your answer here...
C

Discuss how the behaviour of Al2O3Al_2O_3 supports the idea that metallic and non-metallic properties form a continuum.

[2]
Write your answer here...

0

Question 43
HL • Paper 2
Hard
Calculator Permitted

The graph shows first ionization energies for the period 2 elements from lithium to neon.

First ionization energies for the period 2 elements.
A

Consider the general pattern across period 2.

I.

Describe the overall trend in first ionization energy from lithium to neon.

[1]
Write your answer here...
II.

Explain the general increase in first ionization energy across period 2.

[2]
Write your answer here...
B

Consider the two discontinuities in the graph.

I.

Explain why the first ionization energy of boron is lower than that of beryllium.

[2]
Write your answer here...
II.

Explain why the first ionization energy of oxygen is lower than that of nitrogen. Do not base your answer on the phrase special stability of a half-filled sublevel.

[2]
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C

Discuss how these discontinuities provide evidence for the existence of energy sublevels.

[1]
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Question 44
HL • Paper 2
Hard
Calculator Permitted

Scandium, iron and zinc are d-block elements in period 4. Their common species include Sc3+Sc^{3+}, Fe2+Fe^{2+}, Fe3+Fe^{3+} and Zn2+Zn^{2+}.

A

Consider the classification of transition elements.

I.

State the definition of a transition element used in this course.

[1]
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II.

Explain why zinc is not classified as a transition element.

[2]
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III.

Evaluate one argument for and one argument against including scandium as a transition element.

[2]
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B

Explain how incomplete d sublevels account for three characteristic properties of transition element compounds.

[3]
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Question 45
HL • Paper 2
Hard
Calculator Permitted

The first-row transition elements form ions by losing electrons from the 4s4s sublevel before the 3d3d sublevel. A graph comparing successive ionization energies for vanadium and calcium is shown.

Successive ionization energies of vanadium and calcium.
A

Deduce electron configurations of vanadium and copper ions.

I.

Deduce the electron configuration of V3+V^{3+} from the neutral atom.

[2]
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II.

Deduce the electron configurations of Cu+Cu^+ and Cu2+Cu^{2+}.

[2]
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III.

Explain why V5+V^{5+} has the electron configuration [Ar][\text{Ar}].

[1]
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B

Explain why variable oxidation states are common among transition elements.

[2]
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C

Using the graph, suggest why V5+V^{5+} is plausible but Ca5+Ca^{5+} is not.

[1]
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Question 46
HL • Paper 2
Hard
Calculator Permitted

A transition metal complex appears blue-green in aqueous solution. It absorbs visible light of wavelength 6.10×107 m6.10 \times 10^{-7}\ \text{m}. Use c=3.00×108 m s1c = 3.00 \times 10^8\ \text{m s}^{-1}.

A colour wheel showing complementary colours and broad visible wavelength regions. It should allow students to relate absorbed and observed colours without annotating the specific complex in the question.
A

Consider the origin of the colour.

I.

Explain why many transition metal complexes are coloured.

[3]
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II.

Calculate the frequency of the absorbed light.

[2]
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B

The ligand is changed to one that causes a larger d-orbital splitting.

I.

If the dd-orbital splitting increases, predict the effect on the wavelength and frequency of the light absorbed.

[2]
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II.

State one factor, other than ligand identity, that can affect the colour of a transition metal complex.

[1]
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0

Question 47
HL • Paper 2
Hard
Calculator Permitted

A student determines the concentration of a blue solution containing a transition metal complex using colorimetry. A calibration curve of absorbance against concentration is prepared from standard solutions.

Calibration curve for a blue transition-metal complex.
A

Consider the design of the colorimetry method.

I.

Explain why a wavelength near the absorption maximum should be selected.

[2]
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II.

Outline how the calibration curve is prepared.

[2]
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B

The absorbance of a diluted sample corresponds on the calibration curve to 1.60×103 mol dm31.60 \times 10^{-3}\ \text{mol dm}^{-3}. The original sample was diluted by transferring 10.0 cm310.0\ \text{cm}^3 into a 100.0 cm3100.0\ \text{cm}^3 volumetric flask and making up to the mark. Calculate the concentration of the original sample.

[2]
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C

Evaluate two ways to improve or check the reliability of the colorimetry result.

[2]
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0

Question 48
HL • Paper 2
Hard
Calculator Permitted

The ions Fe2+Fe^{2+}, Fe3+Fe^{3+} and Zn2+Zn^{2+} are compared. Iron is also used as a heterogeneous catalyst in some industrial reactions.

A

Consider the electron configurations and magnetic behaviour of the ions.

I.

Deduce the electron configurations of Fe2+Fe^{2+} and Fe3+Fe^{3+}.

[2]
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II.

Explain why compounds containing iron ions may show magnetic properties whereas compounds containing Zn2+Zn^{2+} often do not.

[2]
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B

Discuss why iron can show both catalytic behaviour and variable oxidation states.

[3]
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S2.4 From models to materials

S3.2 Functional groups