The p-block of the periodic table is represented by the shaded region in diagram
The oxide in period 3 that is amphoteric is
An atom has the electron configuration .
The period, group and classification of the element are
period 5, group 17, noble gas
period 3, group 15, halogen
period 3, group 17, halogen
period 3, group 18, noble gas
Chlorine water is added to aqueous potassium iodide.
The equation for the reaction is
The oxidation state of hydrogen in is
The electron configuration of is
A transition metal complex absorbs orange light.
The colour most likely observed is

green
orange
red
blue
A simplified periodic table is shown with three labelled positions, X, Y and Z.

State the name given to a horizontal row in the periodic table.
State the classification of element X and the number of valence electrons in an atom of X.
State the classification of element Y as metal, non-metal or metalloid.
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The species , , and are isoelectronic.
The correct order of ionic radius, from largest to smallest, is
The first ionization energy of aluminium is lower than that of magnesium.
The best explanation is that the electron removed from aluminium is
paired in a orbital, causing electron-electron repulsion
closer to the nucleus because aluminium has a greater nuclear charge
a electron, which is more strongly shielded than a electron
a electron, which is higher in energy than a electron
A transition element is an element that has an incomplete d sublevel in its atoms or forms at least one stable ion with an incomplete d sublevel.
The diagram that represents a transition element is
A coloured complex absorbs light of wavelength .
Using and , the frequency of the absorbed light is
An atom of element E has the electron configuration .
Deduce the period and group number of element E.
Deduce the number of valence electrons and the block of the periodic table to which element E belongs.
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The graph shows periodic trends for selected period 3 elements.
| Element | Atomic radius / pm | Electronegativity (Pauling) |
|---|---|---|
| Na | 186 | 0.93 |
| Mg | 160 | 1.31 |
| Al | 143 | 1.61 |
| Si | 118 | 1.90 |
| P | 110 | 2.19 |
| S | 104 | 2.58 |
| Cl | 99 | 3.16 |
Describe the trend in atomic radius across period 3 from sodium to chlorine.
Explain the trend in atomic radius across period 3.
State the general trend in electronegativity across period 3 from left to right.
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Group 1 metals react with water, and group 17 elements react with halide ions according to their reactivity trends.
Write the balanced equation for the reaction of potassium with water.
Explain why chlorine displaces iodide ions from aqueous potassium iodide, but iodine does not displace chloride ions from aqueous potassium chloride.
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Oxides of elements show a change in acid-base character across a period.
Write the equation for the reaction of sodium oxide with water.
Write the equation for the reaction of sulfur trioxide with water.
Outline how the acid-base character of the oxides changes across period 3 from sodium to sulfur.
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The table gives information about four elements labelled A to D. The letters are not chemical symbols.
| Element | Electron configuration |
|---|---|
| A | [Ne] 3s1 |
| B | [Ne] 3s2 3p4 |
| C | [Ar] 3d6 4s2 |
| D | [Ne] 3s2 3p2 |
Deduce the period and group of element B from its electron configuration.
Identify the block and broad classification of element C.
Suggest why element D is classified as a metalloid rather than simply as a metal or non-metal.
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A simulation compares the reactions of three group 1 metals with excess water under the same conditions.
| Group 1 metal | Time for reaction to finish / s | Temperature increase / °C |
|---|---|---|
| Lithium | 75 | 4 |
| Sodium | 30 | 8 |
| Potassium | 12 | 13 |
State the gas produced in the reactions.
Describe how the reactivity changes from lithium to potassium using the data.
Explain the change in reactivity down group 1.
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Transition elements commonly show variable oxidation states.
The best explanation is that
their filled p sublevels can expand into d sublevels
their atoms have the same first ionization energy across the period
their inner-shell electrons are removed before valence electrons
their and electrons are relatively close in energy
Oxidation states can be deduced using the usual rules and the overall charge of the species.
Deduce the oxidation state of hydrogen in and oxygen in .
Deduce the oxidation state of sulfur in and give the systematic name of this oxyanion using a Roman numeral.
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The graph shows first ionization energies for the elements in period 2.

State the general trend in first ionization energy across period 2.
Explain why the first ionization energy of boron is lower than that of beryllium.
Explain why the first ionization energy of oxygen is lower than that of nitrogen.
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Zinc and scandium are both found in the first row of the d-block, but their classification as transition elements is considered differently.
Define the term transition element.
Explain why zinc is not usually classified as a transition element.
State one characteristic property commonly shown by transition elements that is linked to incomplete d-sublevels.
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Chromium and iron are first-row transition elements.
State the condensed electron configuration of a chromium atom.
Deduce the electron configuration of .
Deduce the electron configuration of , given that is .
State which sublevel loses electrons first when first-row transition metal atoms form ions.
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An aqueous transition metal complex absorbs light of wavelength . Use and .
Calculate the frequency of the light absorbed.
Deduce the colour observed if the absorbed light is orange-red.
State one factor that can affect the colour of a transition metal complex.
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The graph shows first ionization energy, atomic radius and electronegativity for selected period 3 elements.
| Element | First ionization energy / kJ mol^-1 | Atomic radius / pm | Electronegativity / Pauling scale |
|---|---|---|---|
| Sodium (Na) | 496 | 186 | 0.93 |
| Magnesium (Mg) | 738 | 160 | 1.31 |
| Aluminium (Al) | 578 | 143 | 1.61 |
| Silicon (Si) | 787 | 118 | 1.90 |
| Phosphorus (P) | 1012 | 110 | 2.19 |
| Sulfur (S) | 1000 | 104 | 2.58 |
| Chlorine (Cl) | 1251 | 99 | 3.16 |
Describe the trend in atomic radius across the period shown.
Explain the trend in atomic radius across the period.
Use the data to suggest the element in the graph with the strongest attraction for bonding electrons, giving a reason.
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Aqueous halogens were added separately to aqueous solutions containing halide ions. The observations after mixing and shaking are shown.
| Halogen added | Cl⁻(aq) | Br⁻(aq) | I⁻(aq) |
|---|---|---|---|
| Cl₂(aq) | no visible change | solution turns orange-brown | solution turns brown |
| Br₂(aq) | no visible change | no visible change | solution turns brown |
| I₂(aq) | no visible change | no visible change | no visible change |
Identify one mixture in which a displacement reaction occurs.
Write the ionic equation for the reaction between chlorine and bromide ions.
Use the observations to deduce the order of decreasing reactivity of the three halogens.
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The table shows formulae of some compounds and ions containing hydrogen or oxygen. Some oxidation states are missing.
| Species / formula | Given oxidation state(s) | Missing oxidation state |
|---|---|---|
| NaH | Na = +1 | H = ? |
| H2O2 | H = +1 | O = ? |
| NO3− | O = -2 | N = ? |
| Cl2 | — | Cl = ? |
Deduce the oxidation state of hydrogen in sodium hydride, .
Deduce the oxidation state of oxygen in hydrogen peroxide, .
Deduce the oxidation state of nitrogen in .
Explain why chlorine has oxidation state zero in .
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The table compares selected period 4 d-block elements and some of their common ions.
| Element | Atom electron configuration | Common ion(s) / electron configuration |
|---|---|---|
| Sc | [Ar] 4s2 3d1 | Sc2+ = [Ar] 3d1; Sc3+ = [Ar] |
| Ti | [Ar] 4s2 3d2 | Ti2+ = [Ar] 3d2 |
| V | [Ar] 4s2 3d3 | V2+ = [Ar] 3d3 |
| Fe | [Ar] 4s2 3d6 | Fe2+ = [Ar] 3d6 |
| Cu | [Ar] 4s1 3d10 | Cu2+ = [Ar] 3d9 |
| Zn | [Ar] 4s2 3d10 | Zn2+ = [Ar] 3d10 |
Using the data, identify the element that is d-block but is not normally classified as a transition element.
Explain the identification in part (a) using electron configurations.
Evaluate one argument for including scandium as a transition element, based on the data.
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A table compares successive ionization energies for calcium and vanadium after the argon core.
| Ionization energy | Ca / kJ mol^-1 | V / kJ mol^-1 |
|---|---|---|
| 1st | 590 | 650 |
| 2nd | 1145 | 1414 |
| 3rd | 4912 | 2830 |
| 4th | 6491 | 4564 |
| 5th | 8153 | 6290 |
State what is meant by successive ionization energies.
Explain why vanadium can form several oxidation states.
Deduce the electron configuration of , given that is .
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A student uses colorimetry to determine the concentration of a coloured transition metal complex in solution.

Outline how the calibration graph is used to determine the concentration of the unknown solution.
Explain why a wavelength strongly absorbed by the complex is chosen for the colorimeter.
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Several period 3 oxides were added separately to water. Universal indicator and pH data were recorded after stirring.
| Oxide | Indicator colour | pH |
|---|---|---|
| Na2O | purple | 13 |
| MgO | blue | 10 |
| Al2O3 | green | 7 |
| P4O10 | red | 2 |
| SO2 | red | 2 |
Classify sodium oxide and sulfur dioxide as basic, acidic or amphoteric oxides.
Write an equation for the reaction of sodium oxide with water.
Explain why the data support the idea that metallic and non-metallic properties form a continuum across period 3.
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The graph shows the first ionization energies of period 2 elements from lithium to neon.

Describe the overall trend in first ionization energy across period 2.
Explain the discontinuity between beryllium and boron.
Explain the discontinuity between nitrogen and oxygen.
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A transition metal complex appears blue-green in aqueous solution. A colour wheel and absorption spectrum for the solution are shown. Use and .

State the colour of light mainly absorbed by the complex.
Determine the wavelength at maximum absorbance from the spectrum, in metres.
Calculate the frequency of light at maximum absorbance.
Explain why absorption of this light gives rise to the observed colour.
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The table gives neutral atom electron configurations for chromium, iron and copper, and lists some ions formed by these elements.
| Species | Electron configuration |
|---|---|
| Cr | [Ar]4s1 3d5 |
| Cr2+ | [Ar]3d4 |
| Fe | [Ar]4s2 3d6 |
| Fe2+ | [Ar]3d6 |
| Cu | [Ar]4s1 3d10 |
| Cu+ | [Ar]3d10 |
| Zn2+ | [Ar]3d10 |
Deduce the electron configuration of from .
Deduce the electron configuration of from .
Outline the rule used to decide which electrons are removed first when first-row transition metal ions form.
Using the data, suggest why copper(II) compounds are more likely to be coloured than zinc(II) compounds.
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The electron configurations of three neutral atoms are shown.
A:
B:
C:
Consider element A.
Deduce the period, group and block of element A.
Explain why element A and bromine have similar chemical properties.
Compare the classifications of elements B and C as metal, metalloid or non-metal, using their positions in the periodic table.
Hydrogen is often placed above group 1. Suggest why this placement does not make hydrogen an alkali metal.
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The figure shows selected periodic trends for elements in period 3 and group 17.
| Species | Series | Atomic radius / pm | Electronegativity / Pauling | Ionic radius / pm |
|---|---|---|---|---|
| Na | Period 3 | 186 | 0.9 | — |
| Mg | Period 3 | 160 | 1.3 | — |
| Al | Period 3 | 143 | 1.6 | — |
| Si | Period 3 | 118 | 1.9 | — |
| P | Period 3 | 110 | 2.2 | — |
| S | Period 3 | 104 | 2.6 | — |
| Cl | Period 3 | 99 | 3.2 | — |
| F | Group 17 | 64 | 4.0 | — |
| Cl | Group 17 | 99 | 3.2 | — |
| Br | Group 17 | 114 | 3.0 | — |
| I | Group 17 | 133 | 2.7 | — |
| Mg2+ | Ion | — | — | 72 |
Consider the elements from sodium to chlorine in period 3.
Describe the trends in atomic radius and electronegativity across this part of period 3.
Explain the trend in atomic radius across period 3.
Consider the halogens fluorine, chlorine, bromine and iodine.
State the trend in atomic radius down group 17.
Explain why electronegativity and non-metallic character decrease down group 17.
Magnesium commonly forms . Suggest why the ionic radius of is smaller than the atomic radius of Mg.
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Oxidation states are assigned by treating bonds as if they were fully ionic. The species , , , and are considered.
Deduce oxidation states in compounds and ions.
Deduce the oxidation state of oxygen in and hydrogen in .
Deduce the oxidation state of nitrogen in and , and give the systematic names using Roman numerals.
Explain why the oxidation state of chlorine in is zero.
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An element X was predicted before it was isolated. A modern description of X is that its neutral atom has the electron configuration .
Use the electron configuration of X.
Deduce the period, group and block of X.
Deduce the likely identity of X and classify it as a metal, metalloid or non-metal.
Discuss how the organization of the periodic table can help chemists predict properties of undiscovered elements.
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Successive ionization energies are shown for two period 4 elements, X and Y. Element X forms several stable compounds with different oxidation states, whereas element Y mainly forms compounds in one oxidation state.

State what is meant by successive ionization energies.
Use the data to identify which element, X or Y, is more likely to be a transition element.
Explain how the successive ionization energy data account for variable oxidation states in X.
Deduce the electron configuration of from the neutral atom configuration .
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A student used colorimetry to determine the concentration of a coloured transition metal ion in an unknown solution. Standard solutions were prepared and their absorbance was measured at a selected wavelength.

Use the calibration graph to determine the concentration of the unknown solution.
Explain why the wavelength selected should be close to the wavelength of maximum absorbance.
Suggest one source of systematic error in this colorimetric method.
The ligand around the metal ion is changed and the absorption maximum shifts to a shorter wavelength. Explain what this indicates about the split d-sublevels.
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A class compares the reactions of group 1 metals with water and the displacement reactions of halogens with halide ions. Some observations are obtained from teacher demonstrations and some from simulations.
| Reaction system | Observation |
|---|---|
| Lithium(s) + water(l) | gentle effervescence; moves slowly on the surface |
| Sodium(s) + water(l) | vigorous effervescence; metal melts into a ball and moves rapidly |
| Potassium(s) + water(l) | very vigorous effervescence; lilac flame observed |
| Bromine(aq) + chloride ions(aq) | no visible change; orange colour remains |
| Bromine(aq) + bromide ions(aq) | no visible change; orange colour remains |
| Bromine(aq) + iodide ions(aq) | orange solution turns brown |
Potassium is added to water.
Write a balanced equation for potassium reacting with water, including state symbols.
Explain why the reactions of group 1 metals with water become more vigorous down the group.
Deduce whether aqueous bromine reacts with aqueous iodide ions and write the ionic equation if a reaction occurs.
Evaluate the use of simulations rather than direct practical work for these reactivity comparisons.
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Oxides across a period show a change from basic metal oxides through amphoteric oxides to acidic non-metal oxides. The oxides , , and are considered.
Consider the reactions of oxides with water.
Deduce equations for the reactions of and with water.
Predict whether each solution formed in (a)(i) is acidic or alkaline, giving a reason.
Explain, in terms of bonding, why metal oxides tend to be basic while non-metal oxides tend to be acidic.
Discuss how the behaviour of supports the idea that metallic and non-metallic properties form a continuum.
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The graph shows first ionization energies for the period 2 elements from lithium to neon.

Consider the general pattern across period 2.
Describe the overall trend in first ionization energy from lithium to neon.
Explain the general increase in first ionization energy across period 2.
Consider the two discontinuities in the graph.
Explain why the first ionization energy of boron is lower than that of beryllium.
Explain why the first ionization energy of oxygen is lower than that of nitrogen. Do not base your answer on the phrase special stability of a half-filled sublevel.
Discuss how these discontinuities provide evidence for the existence of energy sublevels.
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Scandium, iron and zinc are d-block elements in period 4. Their common species include , , and .
Consider the classification of transition elements.
State the definition of a transition element used in this course.
Explain why zinc is not classified as a transition element.
Evaluate one argument for and one argument against including scandium as a transition element.
Explain how incomplete d sublevels account for three characteristic properties of transition element compounds.
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The first-row transition elements form ions by losing electrons from the sublevel before the sublevel. A graph comparing successive ionization energies for vanadium and calcium is shown.

Deduce electron configurations of vanadium and copper ions.
Deduce the electron configuration of from the neutral atom.
Deduce the electron configurations of and .
Explain why has the electron configuration .
Explain why variable oxidation states are common among transition elements.
Using the graph, suggest why is plausible but is not.
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A transition metal complex appears blue-green in aqueous solution. It absorbs visible light of wavelength . Use .

Consider the origin of the colour.
Explain why many transition metal complexes are coloured.
Calculate the frequency of the absorbed light.
The ligand is changed to one that causes a larger d-orbital splitting.
If the -orbital splitting increases, predict the effect on the wavelength and frequency of the light absorbed.
State one factor, other than ligand identity, that can affect the colour of a transition metal complex.
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A student determines the concentration of a blue solution containing a transition metal complex using colorimetry. A calibration curve of absorbance against concentration is prepared from standard solutions.

Consider the design of the colorimetry method.
Explain why a wavelength near the absorption maximum should be selected.
Outline how the calibration curve is prepared.
The absorbance of a diluted sample corresponds on the calibration curve to . The original sample was diluted by transferring into a volumetric flask and making up to the mark. Calculate the concentration of the original sample.
Evaluate two ways to improve or check the reliability of the colorimetry result.
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The ions , and are compared. Iron is also used as a heterogeneous catalyst in some industrial reactions.
Consider the electron configurations and magnetic behaviour of the ions.
Deduce the electron configurations of and .
Explain why compounds containing iron ions may show magnetic properties whereas compounds containing often do not.
Discuss why iron can show both catalytic behaviour and variable oxidation states.
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