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E.1 Structure of atom

Practice exam-style IB Physics questions for Structure of atom, aligned with the syllabus and grouped by topic.

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Question 1
SL • Paper 1A
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SL • Paper 1A
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In the Geiger--Marsden--Rutherford experiment, alpha particles were directed at a thin gold foil. The observation that most directly required the Thomson model to be replaced was that

A.

most alpha particles passed through the foil without noticeable deflection.

B.

a very small number of alpha particles were scattered through angles greater than 90∘90^\circ.

C.

the alpha particles produced flashes on a fluorescent screen.

D.

the alpha particles travelled through the apparatus in a vacuum.

Question 2
SL • Paper 1A
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SL • Paper 1A
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A nucleus is represented by the notation 2964X{}^{64}_{29}X. The number of neutrons in this nucleus is

A.

3535

B.

6464

C.

9393

D.

2929

Question 3
SL • Paper 1A
Easy
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SL • Paper 1A
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A low-pressure gas emits light that, when viewed through a spectrometer, appears as bright lines at particular wavelengths on a dark background. The conclusion supported by this observation is that atoms of the gas

A.

emit photons whose energies are independent of atomic structure.

B.

can have only certain allowed internal energies.

C.

contain electrons with a continuous range of orbital radii.

D.

absorb all wavelengths more strongly than they emit light.

Question 4
SL • Paper 1A
Easy
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SL • Paper 1A
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An atom in a lower energy level absorbs a photon and moves to a higher energy level. The condition for this absorption to occur is that the photon energy must

A.

equal the energy difference between the two allowed levels.

B.

have the same wavelength as every photon emitted by the atom.

C.

be less than the energy difference between the two levels.

D.

be greater than the energy of the lower level by any amount.

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Question 5
SL • Paper 1A
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SL • Paper 1A
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Light from a star is analysed and several absorption lines are found to have the same pattern of separations as the laboratory spectrum of element YY. The valid inference is that

A.

the atoms of element YY have continuous energy levels in the star.

B.

the absorption lines are produced by the nucleus changing energy level.

C.

the star contains only element YY and no other elements.

D.

element YY is present in the outer layers of the star.

Question 6
HL • Paper 1A
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HL • Paper 1A
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The radius of a nucleus is modelled by R=R0A1/3R=R_0A^{1/3}. The ratio of the radius of a nucleus with A=216A=216 to that of a nucleus with A=27A=27 is

A.

6464

B.

22

C.

88

D.

33

Question 7
HL • Paper 1A
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HL • Paper 1A
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At sufficiently high incident kinetic energies, alpha-particle scattering from a nucleus deviates from the Rutherford prediction. The reason for this deviation is that the alpha particles

A.

approach close enough for the strong nuclear interaction to become significant.

B.

move too slowly for the electric force to act on them.

C.

lose all their positive charge before reaching the nucleus.

D.

are attracted by the electrons with a force larger than the nuclear force.

Question 8
SL • Paper 2
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SL • Paper 2
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A neutral atom is represented by the nuclear notation 1737X{}^{37}_{17}X.

A

Determine the number of protons in the nucleus.

[1]
B

Determine the number of neutrons in the nucleus.

[1]
C

State the number of electrons in the neutral atom.

[1]

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Question 9
SL • Paper 1A
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SL • Paper 1A
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An atom emits a photon when its energy decreases by 3.20 eV3.20\ \text{eV}. The frequency of the photon is approximately

A.

1.3×1015 Hz1.3\times10^{15}\ \text{Hz}

B.

2.1×10−15 Hz2.1\times10^{-15}\ \text{Hz}

C.

7.7×1014 Hz7.7\times10^{14}\ \text{Hz}

D.

4.8×1014 Hz4.8\times10^{14}\ \text{Hz}

Question 10
HL • Paper 1A
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HL • Paper 1A
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For nuclei obeying R=R0A1/3R=R_0A^{1/3}, the approximate nuclear density is independent of AA because

A.

volume is proportional to A1/3A^{1/3} and mass is constant.

B.

mass is proportional to A1/3A^{1/3} and volume is proportional to AA.

C.

radius and mass are both independent of AA.

D.

mass and volume are both proportional to AA.

Question 11
HL • Paper 1A
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HL • Paper 1A
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In a head-on alpha-particle scattering experiment, the distance of closest approach is rcr_c for a target nucleus of proton number ZZ and alpha-particle kinetic energy EαE_\alpha. For a target nucleus with proton number 3Z3Z and alpha-particle kinetic energy 2Eα2E_\alpha, the distance of closest approach is

A.

6rc6r_c

B.

23rc\dfrac{2}{3}r_c

C.

32rc\dfrac{3}{2}r_c

D.

rcr_c

Question 12
HL • Paper 1A
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HL • Paper 1A
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In the Bohr model of hydrogen, En=−13.6/n2 eVE_n=-13.6/n^2\ \text{eV}. The energy of a photon emitted in a transition from n=4n=4 to n=2n=2 is

A.

4.25 eV4.25\ \text{eV}

B.

1.89 eV1.89\ \text{eV}

C.

2.55 eV2.55\ \text{eV}

D.

0.85 eV0.85\ \text{eV}

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Question 13
SL • Paper 2
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SL • Paper 2
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Alpha particles are directed at a thin gold foil in a vacuum. A surrounding fluorescent screen detects the alpha particles after they pass near or through the foil.

A labelled apparatus diagram for the Geiger-Marsden-Rutherford experiment showing an alpha-particle source, a collimated beam, a very thin gold foil, and a surrounding fluorescent screen. The diagram should show most alpha particles continuing nearly straight and a very small number undergoing large-angle deflection, without giving explanatory annotations about the nucleus.
A

State one observation from the experiment that was inconsistent with Thomson's model of the atom.

[1]
B

Explain how the observations led Rutherford to propose a nuclear model of the atom.

[3]
Question 14
SL • Paper 2
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SL • Paper 2
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The visible spectrum from a hot, low-pressure gas contains bright lines at particular wavelengths on a dark background.

An emission line spectrum with several narrow bright coloured lines at separated positions on a dark background. The spectrum should be labelled with increasing wavelength from left to right but should not include numerical wavelength values.
A

State the name given to this type of spectrum.

[1]
B

Explain why this spectrum provides evidence for discrete atomic energy levels.

[3]
Question 15
SL • Paper 2
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SL • Paper 2
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A sample in a flame produces emission lines at 486 nm486\ \text{nm}, 589 nm589\ \text{nm} and 656 nm656\ \text{nm}. Laboratory reference lines include hydrogen at 486 nm486\ \text{nm} and 656 nm656\ \text{nm}, sodium at 589 nm589\ \text{nm}, and calcium at 422 nm422\ \text{nm} and 616 nm616\ \text{nm}.

Unknown sample and reference emission-line wavelengths on a common scale.
A

Identify the elements present in the sample.

[2]
B

Explain why a line spectrum can be used to identify chemical composition.

[1]
Question 16
SL • Paper 2
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SL • Paper 2
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White light passes through a cool, low-pressure gas and then into a spectrometer. Dark lines are observed in the otherwise continuous spectrum.

A labelled diagram showing a continuous white-light source, a cell containing cool low-pressure gas, a spectrometer, and an observed absorption spectrum with dark lines on a continuous background. The diagram should not label the dark lines with specific elements or energy transitions.
A

State what happens to atoms in the gas when photons corresponding to the dark lines pass through it.

[1]
B

Explain why the dark lines remain visible even though the atoms may later emit photons of the same energy.

[2]

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Question 17
HL • Paper 2
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HL • Paper 2
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Rutherford scattering predictions agree with observations for alpha particles of relatively low kinetic energy, but deviations are observed when the incident alpha-particle energy is increased sufficiently.

Observed and Rutherford scattering as alpha-particle energy increases.
A

State the assumption about the interaction between the alpha particle and the target nucleus in Rutherford scattering at low energies.

[1]
B

Explain why deviations from Rutherford scattering occur at high incident energies.

[2]
Question 18
HL • Paper 2
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HL • Paper 2
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For hydrogen, the Bohr energy levels are given by En=−13.6/n2 eVE_n=-13.6/n^2\ \text{eV}.

A

Calculate the minimum energy required to ionize a hydrogen atom initially in the n=3n=3 state.

[2]
B

Explain the significance of the negative value of E3E_3.

[1]
C

State one limitation of the Bohr model of the atom.

[1]
Question 19
SL • Paper 1B
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SL • Paper 1B
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Alpha particles were directed at a very thin gold foil. A detector counted scintillations at different angles from the original alpha-particle direction.

Detector count rate at different scattering angles.
A

Describe the main trend shown by the count-rate data.

[1]
B

State what the detection of alpha particles at angles greater than 90∘90^\circ shows about the force acting on these alpha particles.

[1]
C

Explain how these observations led to the nuclear model of the atom rather than Thomson's model.

[2]
Question 20
SL • Paper 1B
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SL • Paper 1B
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A mass spectrometer separates neutral atoms of a sample into three isotope peaks. The chemical symbol XX is supplied for the element.

Atom

Mass number AA

Proton number ZZ

Relative abundance / %

P

63

29

69.0

Q

65

29

30.0

R

64

30

1.0

A

Determine the neutron number of isotope P, written as 2963X{}^{63}_{29}X.

[1]
B

Identify the two atoms in the table that are isotopes of the same element.

[1]
C

For neutral isotope Q, written as 2965X{}^{65}_{29}X, state the number of electrons and explain your answer.

[2]

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Question 21
SL • Paper 1B
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SL • Paper 1B
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A narrow beam containing photons of several frequencies passes through a cool low-pressure gas. The spectrum is recorded in the original beam direction and also at 90∘90^\circ to the beam.

Annotated stimulus showing a multi-frequency incident light beam entering a cell of cool low-pressure gas, an absorption spectrum recorded after the cell in the forward direction, and weak emission lines detected sideways at wavelengths corresponding to the missing forward-beam lines.
A

State the condition for a photon to be absorbed by an atom in the gas.

[1]
B

Explain why only some frequencies are missing from the forward spectrum after the beam passes through the gas.

[2]
C

Suggest why emission lines can be detected at 90∘90^\circ to the incident beam.

[1]
Question 22
HL • Paper 1A
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HL • Paper 1A
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In the de Broglie interpretation of the Bohr model, an allowed circular orbit has circumference equal to 55 electron de Broglie wavelengths. The angular momentum mvrmvr of the electron in this orbit is

A.

h10π\dfrac{h}{10\pi}

B.

h2π\dfrac{h}{2\pi}

C.

5h2π\dfrac{5h}{2\pi}

D.

10πh10\pi h

Question 23
SL • Paper 2
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SL • Paper 2
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An atom has allowed energy levels at −5.20 eV-5.20\ \text{eV}, −3.10 eV-3.10\ \text{eV} and −1.60 eV-1.60\ \text{eV}. A beam of monochromatic photons of wavelength 590 nm590\ \text{nm} is incident on atoms initially in the lowest of these levels. Use hc=1.24×10−6 eV mhc=1.24\times10^{-6}\ \text{eV m}.

A

Calculate the energy of one incident photon in eV\text{eV}.

[2]
B

Identify the transition that can be produced by absorption of one of these photons.

[1]
C

A photon of wavelength 430 nm430\ \text{nm} is also incident on atoms in the lowest level. Suggest why this photon is not absorbed.

[1]
Question 24
HL • Paper 2
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HL • Paper 2
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A nucleus has nucleon number A=64A=64. Assume that the nuclear radius is given by R=R0A1/3R=R_0A^{1/3}, where R0=1.20×10−15 mR_0=1.20\times10^{-15}\ \text{m}. The unified atomic mass unit is u=1.66×10−27 kgu=1.66\times10^{-27}\ \text{kg}.

A

Calculate the radius of the nucleus.

[1]
B

Calculate the approximate density of the nucleus.

[2]
C

Explain why this model predicts approximately the same density for all nuclei.

[1]

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Question 25
HL • Paper 2
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HL • Paper 2
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In the Bohr model of hydrogen, the energy of level nn is En=−13.6/n2 eVE_n=-13.6/n^2\ \text{eV}. An excited hydrogen atom makes a transition from n=4n=4 to n=2n=2. Use hc=1.24×10−6 eV mhc=1.24\times10^{-6}\ \text{eV m}.

A hydrogen energy-level diagram with horizontal levels labelled by principal quantum number, including $n=1$, $n=2$, $n=3$, $n=4$ and the ionization limit. The levels should be drawn closer together at higher $n$. No transition arrow should be drawn.
A

Calculate the energy of the photon emitted.

[2]
B

Calculate the wavelength of the emitted photon.

[1]
C

State the spectral region of this photon.

[1]
Question 26
HL • Paper 2
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HL • Paper 2
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In the de Broglie interpretation of the Bohr model, an allowed electron orbit forms a standing wave around the circumference of the orbit. For one allowed orbit in hydrogen, n=3n=3 and r=4.76×10−10 mr=4.76\times10^{-10}\ \text{m}. Use me=9.11×10−31 kgm_e=9.11\times10^{-31}\ \text{kg} and h=6.63×10−34 J sh=6.63\times10^{-34}\ \text{J s}.

A circular orbit diagram showing an electron wave fitted around the circumference of an orbit. The diagram should indicate an integer number of wavelengths around the circumference and label the radius $r$, but should not include the angular momentum formula.
A

Use the standing-wave condition to show how Bohr's angular momentum quantization condition follows.

[2]
B

Calculate the electron speed in this orbit.

[2]
Question 27
SL • Paper 1B
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SL • Paper 1B
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The spectra of a hot low-pressure gas and of a continuous source viewed through a cooler sample of the same gas are shown.

Two aligned visible spectra on the same wavelength scale: an emission spectrum with bright narrow lines on a dark background and an absorption spectrum with dark narrow lines in a continuous background. The bright and dark lines for the same gas occur at matching wavelengths.
A

Compare the positions of the bright lines and dark lines shown in the two spectra.

[1]
B

Explain why the presence of lines at only particular wavelengths is evidence for discrete atomic energy levels.

[2]
C

Suggest why the absorption lines appear dark when the continuous spectrum is viewed in the original beam direction.

[1]
Question 28
SL • Paper 1B
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SL • Paper 1B
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An atom has the allowed energy levels shown. A transition labelled T occurs from level E3E_3 to level E1E_1. Use hc=1.24×10−6 eV mhc=1.24\times10^{-6}\ \text{eV m}.

An energy-level diagram with three horizontal levels labelled $E_1$, $E_2$ and $E_3$ on a vertical energy scale in eV. The arrow T is directed downward from the highest of the three levels to the lowest level.
A

State whether transition T represents emission or absorption of a photon.

[1]
B

The energy levels for T are −1.0 eV-1.0\ \text{eV} and −5.0 eV-5.0\ \text{eV}. Calculate the photon energy in eV.

[1]
C

Calculate the wavelength of the photon emitted in transition T.

[2]
D

Explain why a transition with a larger energy difference would produce a photon of shorter wavelength.

[1]

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Question 29
SL • Paper 1B
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SL • Paper 1B
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The absorption spectrum of light from a star is compared with laboratory emission spectra for three elements.

Element

Lab emission wavelengths / nm

Stellar absorption wavelengths / nm

Hydrogen

410.2, 434.0, 486.1, 656.3

660.3

Helium

447.1, 471.3, 492.2, 587.6

451.1, 475.3, 496.2, 591.6

Sodium

589.0, 589.6

593.0, 593.6

A

Identify the elements present in the outer layers of the star from the line pattern.

[2]
B

Explain why the identification should use the whole pattern of lines rather than one matching wavelength.

[1]
C

Suggest what is indicated by the fact that the matching stellar lines are all displaced toward longer wavelengths compared with the laboratory lines.

[1]
Question 30
HL • Paper 2
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HL • Paper 2
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An alpha particle of kinetic energy 5.00 MeV5.00\ \text{MeV} approaches a stationary gold nucleus head-on. The proton number of gold is 7979. Use k=8.99×109 N m2C−2k=8.99\times10^9\ \text{N m}^2\text{C}^{-2}, e=1.60×10−19 Ce=1.60\times10^{-19}\ \text{C} and 1 MeV=1.60×10−13 J1\ \text{MeV}=1.60\times10^{-13}\ \text{J}.

A head-on scattering diagram showing an alpha particle moving directly toward a positively charged target nucleus, momentarily stopping at the distance of closest approach, and then being repelled back along the same line. Label the distance of closest approach as $r_c$ without giving the formula.
A

Calculate the distance of closest approach.

[3]
B

State one physical assumption made in this calculation.

[1]
Question 31
HL • Paper 1B
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HL • Paper 1B
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Measurements of nuclear radius RR for several nuclei are plotted against A1/3A^{1/3}, where AA is the nucleon number. Assume the nuclei are spherical and use u=1.66×10−27 kgu=1.66\times10^{-27}\ \text{kg}.

Measured nuclear radius plotted against A^(1/3).
A

Use the graph to determine R0R_0 in the relationship R=R0A1/3R=R_0A^{1/3}.

[1]
B

Calculate the radius of a nucleus with A=216A=216.

[1]
C

Show that this model predicts approximately the same density for all nuclei and calculate its value.

[3]
Question 32
HL • Paper 1B
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HL • Paper 1B
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Alpha particles are scattered by a gold foil. The graph compares the Rutherford prediction with the measured fraction of alpha particles scattered through angles greater than 90∘90^\circ as the alpha-particle kinetic energy is increased. For gold, Z=79Z=79.

Measured and Rutherford-predicted fractions of alpha particles scattered through more than 90 degrees by gold foil as kinetic energy increases.
A

Describe how the experimental data compare with the Rutherford prediction as the alpha-particle kinetic energy increases.

[2]
B

Explain why deviations from Rutherford scattering occur at sufficiently high alpha-particle energies.

[2]
C

The onset of deviation occurs at about 27 MeV27\ \text{MeV}. Estimate the corresponding distance of closest approach. Use k=8.99×109 N m2 C−2k=8.99\times10^9\ \text{N m}^2\text{ C}^{-2} and e=1.60×10−19 Ce=1.60\times10^{-19}\ \text{C}.

[1]

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Question 33
HL • Paper 1B
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HL • Paper 1B
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An alpha particle approaches a copper nucleus head-on. In the model, the copper nucleus does not recoil and the interaction is only electric repulsion. For copper, Z=29Z=29.

Annotated head-on scattering diagram showing an alpha particle of known speed approaching a stationary copper nucleus, slowing to rest at the distance of closest approach $r_c$, and then being repelled back along the same line. The diagram includes given constants and alpha-particle mass.
A

Calculate the initial kinetic energy of an alpha particle of mass 6.64×10−27 kg6.64\times10^{-27}\ \text{kg} moving at 1.50×107 m s−11.50\times10^7\ \text{m s}^{-1}.

[2]
B

Calculate the distance of closest approach. Use k=8.99×109 N m2 C−2k=8.99\times10^9\ \text{N m}^2\text{ C}^{-2} and e=1.60×10−19 Ce=1.60\times10^{-19}\ \text{C}.

[2]
C

State one reason why this value is not a direct measurement of the nuclear radius.

[1]
Question 34
HL • Paper 1B
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HL • Paper 1B
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The diagram shows some energy levels of hydrogen in the Bohr model. Use En=−13.6/n2 eVE_n=-13.6/n^2\ \text{eV} and hc=1.24×10−6 eV mhc=1.24\times10^{-6}\ \text{eV m}.

Energy-level diagram for hydrogen showing horizontal levels for several principal quantum numbers $n$, with zero energy at ionization and negative bound-state energies. A downward transition from $n=4$ to $n=2$ is labelled.
A

Calculate the energy of the n=4n=4 level.

[1]
B

Calculate the photon energy for the transition from n=4n=4 to n=2n=2.

[1]
C

Calculate the wavelength of the emitted photon.

[2]
D

Identify the spectral series of this transition and state the region of the electromagnetic spectrum.

[1]
Question 35
SL • Paper 2
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SL • Paper 2
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A narrow beam of alpha particles is directed at a very thin gold foil in an evacuated chamber. A movable fluorescent screen detects the alpha particles after they interact with the foil.

A labelled schematic of the Geiger-Marsden-Rutherford apparatus showing an alpha source in a lead block, a narrow collimated alpha-particle beam, a thin gold foil at the centre, an evacuated chamber, and a movable fluorescent screen arranged around the foil. The diagram should show possible paths including mostly straight-through particles and some deflected particles, without quantifying the relative numbers.
A

The observations are summarized qualitatively as: most particles passed through the foil, some were deflected slightly, and a very small number were deflected through large angles.

I.

Explain why most alpha particles passed through the foil with little or no deflection.

[2]
II.

State what the large-angle deflections imply about the charge of the nucleus.

[1]
B

Discuss how these observations led to a change from the Thomson model to the Rutherford nuclear model.

[4]
Question 36
SL • Paper 2
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SL • Paper 2
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Two neutral atoms are represented by the nuclear notation 2963X{}^{63}_{29}X and 2965X{}^{65}_{29}X. The chemical symbol XX is not required.

A

Use the nuclear notation to identify the particles in the two atoms.

I.

Determine the number of protons and electrons in each neutral atom.

[1]
II.

Determine the number of neutrons in each nucleus.

[2]
B

Explain why the two atoms are atoms of the same element but are different isotopes.

[3]

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Question 37
SL • Paper 2
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SL • Paper 2
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Several models have been used to describe atoms. A simple hard-sphere model can be useful in kinetic theory, the Thomson model included electrons embedded in positive charge, and the Rutherford model introduced a small central nucleus.

A

Compare the Thomson and Rutherford models of the atom.

I.

State one feature common to the Thomson and Rutherford models.

[1]
II.

Describe two important differences between the Thomson and Rutherford models.

[2]
B

Evaluate the statement: "An older atomic model is useless once a newer model is introduced."

[4]
Question 38
HL • Paper 1B
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HL • Paper 1B
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In the Bohr model, an allowed electron orbit may be represented by a standing de Broglie wave around a circular path. For the orbit shown, n=3n=3 and r=4.76×10−10 mr=4.76\times10^{-10}\ \text{m}. Use h=6.63×10−34 J sh=6.63\times10^{-34}\ \text{J s} and me=9.11×10−31 kgm_e=9.11\times10^{-31}\ \text{kg}.

Diagram comparing an allowed circular standing wave that fits exactly around the orbit with a non-allowed wave that does not join smoothly. The allowed orbit is labelled with $n=3$, radius $r$, circumference $2\pi r$ and three wavelengths around the circumference.
A

Calculate the de Broglie wavelength of the electron in this orbit.

[1]
B

Use the de Broglie relation to calculate the electron speed in the orbit.

[2]
C

Show that the standing-wave condition leads to Bohr's angular momentum quantization condition for this orbit.

[1]
D

Explain why a wave that does not join smoothly after one circuit is not an allowed stationary orbit in this model.

[1]
Question 39
HL • Paper 1B
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HL • Paper 1B
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High-resolution spectra are compared with predictions from the Bohr model.

Spectrum

Line / transition

Bohr prediction / nm

Observed position / nm

Hydrogen

n=3→2n=3 \to 2

656.3

656.3

Hydrogen

n=4→2n=4 \to 2

486.1

486.1

Hydrogen

n=5→2n=5 \to 2

434.0

434.0

Hydrogen

n=6→2n=6 \to 2

410.2

410.2

Atom X

line 1

589.3

589.0 / 589.6

Atom X

line 2

330.1

330.8

Atom X

line 3

285.3

284.7

A

Identify one observation in the data that the simple Bohr model does not fully explain.

[1]
B

Explain why the Bohr formula for hydrogen is not expected to predict accurately the spectrum of a multi-electron atom.

[2]
C

Evaluate the usefulness of the Bohr model in light of the spectral data.

[1]
Question 40
SL • Paper 2
Hard
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SL • Paper 2
Hard
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A low-pressure gas is placed in a discharge tube. The light from the tube is viewed through a spectrometer. Several bright lines are observed against a dark background.

A spectrometer view showing a dark background crossed by several narrow bright vertical spectral lines of different colours or wavelengths. The lines should be separated irregularly to suggest a characteristic emission line spectrum. No numerical wavelength labels are shown.
A

Explain how the observation of a line spectrum provides evidence for discrete energy levels in atoms.

I.

State what is meant by a discrete energy level.

[1]
II.

Explain why bright lines rather than a continuous spectrum are produced.

[3]
B

One of the bright lines corresponds to a photon of wavelength 486 nm486\ \text{nm}.

I.

Calculate the frequency of the photon.

[2]
II.

Calculate the energy difference between the atomic levels in eV.

[2]

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Question 41
SL • Paper 2
Hard
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SL • Paper 2
Hard
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The absorption spectrum of light from a star is compared with laboratory spectra of three elements. Several dark lines in the star spectrum coincide with lines in the laboratory spectra.

Four horizontal spectral strips on a common wavelength scale: one labelled star and three labelled element A, element B, element C. The star strip is a continuous spectrum with several narrow dark absorption lines. Each element strip shows a pattern of narrow lines. Some, but not all, lines in the star spectrum align vertically with lines in two of the element strips; the third element has a clearly different pattern. No exact wavelengths are printed.
A

Explain why the pattern of spectral lines can be used to identify elements in the star.

I.

State why each element has a characteristic line spectrum.

[1]
II.

Explain how matching the star spectrum with laboratory spectra indicates chemical composition.

[2]
B

Discuss why identifying an element from a single absorption line is less reliable than identifying it from a pattern of several lines.

[4]
Question 42
SL • Paper 2
Hard
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SL • Paper 2
Hard
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An atom has three allowed energy levels: ground state E1=0E_1=0, first excited state E2=2.10 eVE_2=2.10\ \text{eV} and second excited state E3=4.00 eVE_3=4.00\ \text{eV}. The zero of energy is chosen at the ground state for this question.

A simple vertical energy-level diagram with three horizontal levels labelled ground state, first excited state and second excited state. An energy axis is labelled Energy / eV. No transition arrows are drawn.
A

Consider an atom initially in the ground state.

I.

Explain why a photon of energy 1.50 eV1.50\ \text{eV} is not absorbed by the atom when it is in the ground state.

[2]
II.

Calculate the frequency of a photon that can excite the atom from the ground state to the first excited state.

[2]
B

The atom is now in the second excited state.

I.

Determine the possible photon energies emitted as the atom returns to lower energy states.

[2]
II.

Explain why the emitted photons are not necessarily travelling in the same direction as any photon that was originally absorbed.

[2]
Question 43
HL • Paper 2
Hard
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HL • Paper 2
Hard
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For a 82208Pb{}^{208}_{82}\text{Pb} nucleus, the radius RR is modelled by R=R0A1/3R=R_0A^{1/3}, where R0=1.20×10−15 mR_0=1.20\times 10^{-15}\ \text{m}. The mass of one nucleon may be taken as 1.66×10−27 kg1.66\times 10^{-27}\ \text{kg}.

A

Consider a 82208X{}^{208}_{82}X nucleus.

I.

Calculate the radius of the nucleus.

[2]
II.

Estimate the density of the nucleus.

[2]
B

Evaluate the conclusion that all nuclei have approximately the same density in this model.

[4]
Question 44
HL • Paper 2
Hard
Calculator Permitted
HL • Paper 2
Hard
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An alpha particle with kinetic energy 5.0 MeV5.0\ \text{MeV} is directed head-on towards a stationary gold nucleus with proton number Z=79Z=79. Assume that only electric repulsion acts and that the gold nucleus does not recoil.

A one-dimensional head-on scattering diagram showing an alpha particle approaching a positively charged target nucleus along a straight line. The initial kinetic energy is labelled on the incoming path. The closest approach position is marked with a separation labelled $r_c$. No numerical value of $r_c$ is shown.
A

Use energy conservation for the head-on collision.

I.

Explain why the alpha particle momentarily stops at the distance of closest approach.

[1]
II.

Calculate the distance of closest approach.

[3]
B

Discuss what this calculation can and cannot tell us about the size of the gold nucleus.

[4]

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Question 45
HL • Paper 2
Hard
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HL • Paper 2
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In the Bohr model for hydrogen the energy of level nn is En=−13.6/n2 eVE_n=-13.6/n^2\ \text{eV}.

A

A hydrogen atom initially in the ground state absorbs radiation.

I.

Calculate the energy required to excite the atom from n=1n=1 to n=3n=3.

[2]
II.

Calculate the wavelength of the photon that can cause this transition.

[2]
B

The atom in the n=3n=3 state subsequently emits a photon in a transition to n=2n=2.

I.

Show that the photon emitted in the n=3→n=2n=3 \to n=2 transition is in the visible region.

[3]
II.

Explain why transitions ending at n=1n=1 have higher photon energies than transitions ending at n=2n=2 from similar upper levels.

[1]
Question 46
HL • Paper 2
Hard
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HL • Paper 2
Hard
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Alpha particles of increasing kinetic energy are scattered by a thin metal foil. At low energies the angular distribution agrees with Rutherford scattering, but above a certain energy the measured distribution begins to differ from the Rutherford prediction.

Scattered intensity versus angle for alpha particles at 5 MeV and 10 MeV.
A

Explain the physical assumption behind Rutherford scattering at low energies.

I.

State the force assumed to act between the alpha particle and the target nucleus.

[1]
II.

Explain why this assumption is more valid at low incident energies.

[2]
B

Evaluate how the observed high-energy deviations can provide information about nuclear size.

[4]
Question 47
HL • Paper 2
Hard
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HL • Paper 2
Hard
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Bohr proposed that the angular momentum of the electron in a hydrogen atom is quantized according to mvr=nh/(2π)mvr=nh/(2\pi). A de Broglie interpretation treats the electron as a wave around a circular orbit.

Two circular orbit sketches for an electron wave around a nucleus. One circle shows a wave pattern joining smoothly after one circumference, labelled allowed standing wave. The other shows a wave pattern that does not join smoothly, labelled not an allowed standing wave. No numerical wavelengths or radii are shown.
A

Use the standing-wave picture for the electron.

I.

State the standing-wave condition for a stable circular orbit.

[1]
II.

Show how this condition leads to Bohr's angular momentum quantization.

[2]
B

Discuss how quantized angular momentum helps explain discrete atomic energy levels and why this is not a complete model of atoms.

[4]
Question 48
HL • Paper 2
Hard
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HL • Paper 2
Hard
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A simplified hydrogen atom is initially in the n=4n=4 state. In the Bohr model for hydrogen, En=−13.6/n2 eVE_n=-13.6/n^2\ \text{eV} and the zero of energy corresponds to ionization.

A hydrogen energy-level diagram with horizontal levels labelled $n=1$, $n=2$, $n=3$, $n=4$ and an upper ionization level at zero energy. The vertical axis is labelled Energy / eV. The levels get closer together near zero energy. No transition arrows are drawn.
A

Consider the energy of the atom in the n=4n=4 state.

I.

Calculate the energy of the atom in the n=4n=4 state.

[1]
II.

Determine the minimum photon energy required to ionize the atom from the n=4n=4 state.

[1]
III.

Calculate the wavelength of a photon with this minimum ionization energy.

[2]
B

Evaluate the usefulness and limitations of the Bohr model in explaining atomic spectra.

[4]

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E.2 Quantum physics